Ring-Rearrangement Metathesis (RRM) Mediated by Ruthenium-Indenylidene Complexes

Herve Clavier; Julie Broggi; Steven Patrick Nolan

doi:10.1002/ejoc.200901316

Ring-Rearrangement Metathesis (RRM) Mediated by Ruthenium-Indenylidene Complexes

Herve Clavier, Julie Broggi, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

Several ruthenium-indenylidene complexes bearing N-heterocyclic carbenes (NHCs) and phosphanes have been investigated for the ring rearrangement of cyclic compounds by alkene metathesis. These catalysts were found to promote efficiently such domino reactions, especially sterically hindered NHC-containing complexes. Moreover, indenylidene-type catalysts were compared to benzylidene- and Hoveyda-type analogues. The scope of the reaction highlights the parameters governing the RRM.

Original language	English
Pages (from-to)	937-943
Number of pages	7
Journal	European Journal of Organic Chemistry
Issue number	5
DOIs	https://doi.org/10.1002/ejoc.200901316
Publication status	Published - Feb 2010

Keywords

Metathesis
Ruthenium
Nitrogen heterocycles
Carbene ligands
Phosphanes
Rearrangment
N-HETEROCYCLIC CARBENE
OLEFIN METATHESIS
DOMINO METATHESIS
ENYNE METATHESIS
CROSS-METATHESIS
NEW-GENERATION
ROM-RCM
CATALYSTS
LIGANDS
BEARING

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10.1002/ejoc.200901316

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@article{072b0e7d4a0440f7a5e1a8e09ba88903,

title = "Ring-Rearrangement Metathesis (RRM) Mediated by Ruthenium-Indenylidene Complexes",

abstract = "Several ruthenium-indenylidene complexes bearing N-heterocyclic carbenes (NHCs) and phosphanes have been investigated for the ring rearrangement of cyclic compounds by alkene metathesis. These catalysts were found to promote efficiently such domino reactions, especially sterically hindered NHC-containing complexes. Moreover, indenylidene-type catalysts were compared to benzylidene- and Hoveyda-type analogues. The scope of the reaction highlights the parameters governing the RRM.",

keywords = "Metathesis, Ruthenium, Nitrogen heterocycles, Carbene ligands, Phosphanes, Rearrangment, N-HETEROCYCLIC CARBENE, OLEFIN METATHESIS, DOMINO METATHESIS, ENYNE METATHESIS, CROSS-METATHESIS, NEW-GENERATION, ROM-RCM, CATALYSTS, LIGANDS, BEARING",

author = "Herve Clavier and Julie Broggi and Nolan, {Steven Patrick}",

year = "2010",

month = feb,

doi = "10.1002/ejoc.200901316",

language = "English",

pages = "937--943",

journal = "European Journal of Organic Chemistry",

issn = "1434-193X",

publisher = "Wiley-VCH, Weinheim",

number = "5",

}

TY - JOUR

T1 - Ring-Rearrangement Metathesis (RRM) Mediated by Ruthenium-Indenylidene Complexes

AU - Clavier, Herve

AU - Broggi, Julie

AU - Nolan, Steven Patrick

PY - 2010/2

Y1 - 2010/2

N2 - Several ruthenium-indenylidene complexes bearing N-heterocyclic carbenes (NHCs) and phosphanes have been investigated for the ring rearrangement of cyclic compounds by alkene metathesis. These catalysts were found to promote efficiently such domino reactions, especially sterically hindered NHC-containing complexes. Moreover, indenylidene-type catalysts were compared to benzylidene- and Hoveyda-type analogues. The scope of the reaction highlights the parameters governing the RRM.

AB - Several ruthenium-indenylidene complexes bearing N-heterocyclic carbenes (NHCs) and phosphanes have been investigated for the ring rearrangement of cyclic compounds by alkene metathesis. These catalysts were found to promote efficiently such domino reactions, especially sterically hindered NHC-containing complexes. Moreover, indenylidene-type catalysts were compared to benzylidene- and Hoveyda-type analogues. The scope of the reaction highlights the parameters governing the RRM.

KW - Metathesis

KW - Ruthenium

KW - Nitrogen heterocycles

KW - Carbene ligands

KW - Phosphanes

KW - Rearrangment

KW - N-HETEROCYCLIC CARBENE

KW - OLEFIN METATHESIS

KW - DOMINO METATHESIS

KW - ENYNE METATHESIS

KW - CROSS-METATHESIS

KW - NEW-GENERATION

KW - ROM-RCM

KW - CATALYSTS

KW - LIGANDS

KW - BEARING

UR - http://www.scopus.com/inward/record.url?scp=76149101592&partnerID=8YFLogxK

U2 - 10.1002/ejoc.200901316

DO - 10.1002/ejoc.200901316

M3 - Article

SN - 1434-193X

SP - 937

EP - 943

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

IS - 5

ER -

Ring-Rearrangement Metathesis (RRM) Mediated by Ruthenium-Indenylidene Complexes

Abstract

Keywords

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EUMET: EU FP7 'EUMET' Olefin Metathesis as a Practical Synthetic Tool

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Ring-Rearrangement Metathesis (RRM) Mediated by Ruthenium-Indenylidene Complexes

Abstract

Keywords

Access to Document

Other files and links

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Projects

EUMET: EU FP7 'EUMET' Olefin Metathesis as a Practical Synthetic Tool

Cite this