Rhodium catalysed hydroformylation of unsaturated esters

Matthew L Clarke

doi:10.1016/j.tetlet.2004.03.168

Rhodium catalysed hydroformylation of unsaturated esters

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Abstract

Rhodium catalysed hydroformylation of unsaturated esters has been studied. A pronounced temperature dependence was observed on the regioselectivity and catalytic activity for these reactions. and under the appropriate conditions, it is possible to obtain preferentially either linear or quaternary products. A quaternary selective hydroformylation of methyl atropate to give 1,3-aldehydic esters has also been developed. (C) 2004 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	4043-4045
Number of pages	3
Journal	Tetrahedron Letters
Volume	45
DOIs	https://doi.org/10.1016/j.tetlet.2004.03.168
Publication status	Published - 17 May 2004

Keywords

hydroformylation
alkoxycarbonylation
regioselective C-C bond formation
quaternary carbons
phosphite
rhodium
ASYMMETRIC HYDROFORMYLATION
COMPLEXES
CARBONYLATION
DERIVATIVES
PHOSPHINE
LIGANDS
OLEFINS

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10.1016/j.tetlet.2004.03.168

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title = "Rhodium catalysed hydroformylation of unsaturated esters",

abstract = "Rhodium catalysed hydroformylation of unsaturated esters has been studied. A pronounced temperature dependence was observed on the regioselectivity and catalytic activity for these reactions. and under the appropriate conditions, it is possible to obtain preferentially either linear or quaternary products. A quaternary selective hydroformylation of methyl atropate to give 1,3-aldehydic esters has also been developed. (C) 2004 Elsevier Ltd. All rights reserved.",

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doi = "10.1016/j.tetlet.2004.03.168",

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AU - Clarke, Matthew L

PY - 2004/5/17

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AB - Rhodium catalysed hydroformylation of unsaturated esters has been studied. A pronounced temperature dependence was observed on the regioselectivity and catalytic activity for these reactions. and under the appropriate conditions, it is possible to obtain preferentially either linear or quaternary products. A quaternary selective hydroformylation of methyl atropate to give 1,3-aldehydic esters has also been developed. (C) 2004 Elsevier Ltd. All rights reserved.

KW - hydroformylation

KW - alkoxycarbonylation

KW - regioselective C-C bond formation

KW - quaternary carbons

KW - phosphite

KW - rhodium

KW - ASYMMETRIC HYDROFORMYLATION

KW - COMPLEXES

KW - CARBONYLATION

KW - DERIVATIVES

KW - PHOSPHINE

KW - LIGANDS

KW - OLEFINS

UR - http://www.scopus.com/inward/record.url?scp=2342576991&partnerID=8YFLogxK

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DO - 10.1016/j.tetlet.2004.03.168

M3 - Article

SN - 0040-4039

VL - 45

SP - 4043

EP - 4045

JO - Tetrahedron Letters

JF - Tetrahedron Letters

ER -

Rhodium catalysed hydroformylation of unsaturated esters

Abstract

Keywords

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