Rhodium catalysed hydroformylation of unsaturated esters

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Abstract

Rhodium catalysed hydroformylation of unsaturated esters has been studied. A pronounced temperature dependence was observed on the regioselectivity and catalytic activity for these reactions. and under the appropriate conditions, it is possible to obtain preferentially either linear or quaternary products. A quaternary selective hydroformylation of methyl atropate to give 1,3-aldehydic esters has also been developed. (C) 2004 Elsevier Ltd. All rights reserved.

Original languageEnglish
Pages (from-to)4043-4045
Number of pages3
JournalTetrahedron Letters
Volume45
DOIs
Publication statusPublished - 17 May 2004

Keywords

  • hydroformylation
  • alkoxycarbonylation
  • regioselective C-C bond formation
  • quaternary carbons
  • phosphite
  • rhodium
  • ASYMMETRIC HYDROFORMYLATION
  • COMPLEXES
  • CARBONYLATION
  • DERIVATIVES
  • PHOSPHINE
  • LIGANDS
  • OLEFINS

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