Rhodium catalysed hydroformylation of unsaturated esters

Matthew Lee Clarke

doi:10.1016/j.tetlet.2004.03.168

Rhodium catalysed hydroformylation of unsaturated esters

Research output: Contribution to journal › Article › peer-review

Abstract

Rhodium catalysed hydroformylation of unsaturated esters has been studied. A pronounced temperature dependence was observed on the regioselectivity and catalytic activity for these reactions. and under the appropriate conditions, it is possible to obtain preferentially either linear or quaternary products. A quaternary selective hydroformylation of methyl atropate to give 1,3-aldehydic esters has also been developed. (C) 2004 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	4043-4045
Number of pages	3
Journal	Tetrahedron Letters
Volume	45
DOIs	https://doi.org/10.1016/j.tetlet.2004.03.168
Publication status	Published - 17 May 2004

Keywords

hydroformylation
alkoxycarbonylation
regioselective C-C bond formation
quaternary carbons
phosphite
rhodium
ASYMMETRIC HYDROFORMYLATION
COMPLEXES
CARBONYLATION
DERIVATIVES
PHOSPHINE
LIGANDS
OLEFINS

Access to Document

10.1016/j.tetlet.2004.03.168

Cite this

@article{33a7d8d016e948b0951abc0cb95da631,

title = "Rhodium catalysed hydroformylation of unsaturated esters",

abstract = "Rhodium catalysed hydroformylation of unsaturated esters has been studied. A pronounced temperature dependence was observed on the regioselectivity and catalytic activity for these reactions. and under the appropriate conditions, it is possible to obtain preferentially either linear or quaternary products. A quaternary selective hydroformylation of methyl atropate to give 1,3-aldehydic esters has also been developed. (C) 2004 Elsevier Ltd. All rights reserved.",

keywords = "hydroformylation, alkoxycarbonylation, regioselective C-C bond formation, quaternary carbons, phosphite, rhodium, ASYMMETRIC HYDROFORMYLATION, COMPLEXES, CARBONYLATION, DERIVATIVES, PHOSPHINE, LIGANDS, OLEFINS",

author = "Clarke, {Matthew Lee}",

year = "2004",

month = may,

day = "17",

doi = "10.1016/j.tetlet.2004.03.168",

language = "English",

volume = "45",

pages = "4043--4045",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "PERGAMON-ELSEVIER SCIENCE LTD",

}

TY - JOUR

T1 - Rhodium catalysed hydroformylation of unsaturated esters

AU - Clarke, Matthew Lee

PY - 2004/5/17

Y1 - 2004/5/17

N2 - Rhodium catalysed hydroformylation of unsaturated esters has been studied. A pronounced temperature dependence was observed on the regioselectivity and catalytic activity for these reactions. and under the appropriate conditions, it is possible to obtain preferentially either linear or quaternary products. A quaternary selective hydroformylation of methyl atropate to give 1,3-aldehydic esters has also been developed. (C) 2004 Elsevier Ltd. All rights reserved.

AB - Rhodium catalysed hydroformylation of unsaturated esters has been studied. A pronounced temperature dependence was observed on the regioselectivity and catalytic activity for these reactions. and under the appropriate conditions, it is possible to obtain preferentially either linear or quaternary products. A quaternary selective hydroformylation of methyl atropate to give 1,3-aldehydic esters has also been developed. (C) 2004 Elsevier Ltd. All rights reserved.

KW - hydroformylation

KW - alkoxycarbonylation

KW - regioselective C-C bond formation

KW - quaternary carbons

KW - phosphite

KW - rhodium

KW - ASYMMETRIC HYDROFORMYLATION

KW - COMPLEXES

KW - CARBONYLATION

KW - DERIVATIVES

KW - PHOSPHINE

KW - LIGANDS

KW - OLEFINS

UR - http://www.scopus.com/inward/record.url?scp=2342576991&partnerID=8YFLogxK

U2 - 10.1016/j.tetlet.2004.03.168

DO - 10.1016/j.tetlet.2004.03.168

M3 - Article

SN - 0040-4039

VL - 45

SP - 4043

EP - 4045

JO - Tetrahedron Letters

JF - Tetrahedron Letters

ER -

Rhodium catalysed hydroformylation of unsaturated esters

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this