Remarkable S,N,S tridentate chelation to palladium(II) by the monoanion derived from [Ph2P(S)NH]2CO

P Bhattacharyya, Alexandra Martha Zoya Slawin, John Derek Woollins

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9 Citations (Scopus)

Abstract

The reaction between [PdCl2(PhCN)(2)] and [Ph2P(S)NH](2)C=O (H2L) proceeds with monodeprotonation of an amine group in the disulfide ligand to give [Pd(HL)Cl] 1, in which the (HL)(-) anion supplies an S,N,S' donor set to palladium(II), leading to disparate S,N chelate ring sizes at the metal.

Original languageEnglish
Pages (from-to)1545-1546
Number of pages2
JournalJournal of the Chemical Society, Dalton Transactions
Issue number10
DOIs
Publication statusPublished - 2000

Keywords

  • CRYSTAL-STRUCTURES
  • COMPLEXES

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