Remarkable S,N,S tridentate chelation to palladium(II) by the monoanion derived from [Ph2P(S)NH]2CO

P Bhattacharyya; Alexandra Martha Zoya Slawin; John Derek Woollins

doi:10.1039/b002413i

Remarkable S,N,S tridentate chelation to palladium(II) by the monoanion derived from [Ph₂P(S)NH]₂CO

P Bhattacharyya, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction between [PdCl2(PhCN)(2)] and [Ph2P(S)NH](2)C=O (H2L) proceeds with monodeprotonation of an amine group in the disulfide ligand to give [Pd(HL)Cl] 1, in which the (HL)(-) anion supplies an S,N,S' donor set to palladium(II), leading to disparate S,N chelate ring sizes at the metal.

Original language	English
Pages (from-to)	1545-1546
Number of pages	2
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	10
DOIs	https://doi.org/10.1039/b002413i
Publication status	Published - 2000

Keywords

CRYSTAL-STRUCTURES
COMPLEXES

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10.1039/b002413i

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title = "Remarkable S,N,S tridentate chelation to palladium(II) by the monoanion derived from [Ph2P(S)NH]2CO",

abstract = "The reaction between [PdCl2(PhCN)(2)] and [Ph2P(S)NH](2)C=O (H2L) proceeds with monodeprotonation of an amine group in the disulfide ligand to give [Pd(HL)Cl] 1, in which the (HL)(-) anion supplies an S,N,S' donor set to palladium(II), leading to disparate S,N chelate ring sizes at the metal.",

keywords = "CRYSTAL-STRUCTURES, COMPLEXES",

author = "P Bhattacharyya and Slawin, {Alexandra Martha Zoya} and Woollins, {John Derek}",

year = "2000",

doi = "10.1039/b002413i",

language = "English",

pages = "1545--1546",

journal = "Journal of the Chemical Society, Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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T1 - Remarkable S,N,S tridentate chelation to palladium(II) by the monoanion derived from [Ph2P(S)NH]2CO

AU - Bhattacharyya, P

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

PY - 2000

Y1 - 2000

N2 - The reaction between [PdCl2(PhCN)(2)] and [Ph2P(S)NH](2)C=O (H2L) proceeds with monodeprotonation of an amine group in the disulfide ligand to give [Pd(HL)Cl] 1, in which the (HL)(-) anion supplies an S,N,S' donor set to palladium(II), leading to disparate S,N chelate ring sizes at the metal.

AB - The reaction between [PdCl2(PhCN)(2)] and [Ph2P(S)NH](2)C=O (H2L) proceeds with monodeprotonation of an amine group in the disulfide ligand to give [Pd(HL)Cl] 1, in which the (HL)(-) anion supplies an S,N,S' donor set to palladium(II), leading to disparate S,N chelate ring sizes at the metal.

KW - CRYSTAL-STRUCTURES

KW - COMPLEXES

UR - http://www.scopus.com/inward/record.url?scp=0002864254&partnerID=8YFLogxK

U2 - 10.1039/b002413i

DO - 10.1039/b002413i

M3 - Article

SN - 0300-9246

SP - 1545

EP - 1546

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 10

ER -

Remarkable S,N,S tridentate chelation to palladium(II) by the monoanion derived from [Ph₂P(S)NH]₂CO

Abstract

Keywords

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