Relative selectivities in bromination reactions - A note of warning

D. S. Ashton; J. M. Tedder; J. C. Walton

doi:10.1039/C29710001487

Relative selectivities in bromination reactions - A note of warning

D. S. Ashton, J. M. Tedder, J. C. Walton^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Hydrogen bromide is shown to have a pronounced effect on atomic brominations in the gas phase; this is due to two effects, (i) a possible reversible reaction of alkyl radicals with hydrogen bromide, and (ii) the direct reaction between hydrogen bromide and alkyl bromides leading to olefins.

Original language	English
Pages (from-to)	1487-1489
Number of pages	3
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	22
DOIs	https://doi.org/10.1039/C29710001487
Publication status	Published - 1 Jan 1971

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title = "Relative selectivities in bromination reactions - A note of warning",

abstract = "Hydrogen bromide is shown to have a pronounced effect on atomic brominations in the gas phase; this is due to two effects, (i) a possible reversible reaction of alkyl radicals with hydrogen bromide, and (ii) the direct reaction between hydrogen bromide and alkyl bromides leading to olefins.",

author = "Ashton, \{D. S.\} and Tedder, \{J. M.\} and Walton, \{J. C.\}",

year = "1971",

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N2 - Hydrogen bromide is shown to have a pronounced effect on atomic brominations in the gas phase; this is due to two effects, (i) a possible reversible reaction of alkyl radicals with hydrogen bromide, and (ii) the direct reaction between hydrogen bromide and alkyl bromides leading to olefins.

AB - Hydrogen bromide is shown to have a pronounced effect on atomic brominations in the gas phase; this is due to two effects, (i) a possible reversible reaction of alkyl radicals with hydrogen bromide, and (ii) the direct reaction between hydrogen bromide and alkyl bromides leading to olefins.

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DO - 10.1039/C29710001487

M3 - Article

AN - SCOPUS:37049134363

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JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

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Relative selectivities in bromination reactions - A note of warning

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