Regioselectivity in the formation of cyclic sulphones from 4- and 5-alkenesulphonyl chlorides

Peter N. Culshaw; John C. Walton

doi:10.1016/S0040-4039(00)97084-9

Regioselectivity in the formation of cyclic sulphones from 4- and 5-alkenesulphonyl chlorides

Peter N. Culshaw^*, John C. Walton

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Alk-4-enesulphonyl chlorides and alk-5-enesulphonyl chlorides cyclise under free radical conditions mainly in the endo mode to give tetrahydrothiopyran-1,1-dioxide and thiepane- 1,1-dioxide respectively.

Original language	English
Pages (from-to)	6433-6436
Number of pages	4
Journal	Tetrahedron Letters
Volume	31
Issue number	44
DOIs	https://doi.org/10.1016/S0040-4039(00)97084-9
Publication status	Published - 1 Jan 1990

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title = "Regioselectivity in the formation of cyclic sulphones from 4- and 5-alkenesulphonyl chlorides",

abstract = "Alk-4-enesulphonyl chlorides and alk-5-enesulphonyl chlorides cyclise under free radical conditions mainly in the endo mode to give tetrahydrothiopyran-1,1-dioxide and thiepane- 1,1-dioxide respectively.",

author = "Culshaw, {Peter N.} and Walton, {John C.}",

year = "1990",

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doi = "10.1016/S0040-4039(00)97084-9",

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T1 - Regioselectivity in the formation of cyclic sulphones from 4- and 5-alkenesulphonyl chlorides

AU - Culshaw, Peter N.

AU - Walton, John C.

PY - 1990/1/1

Y1 - 1990/1/1

N2 - Alk-4-enesulphonyl chlorides and alk-5-enesulphonyl chlorides cyclise under free radical conditions mainly in the endo mode to give tetrahydrothiopyran-1,1-dioxide and thiepane- 1,1-dioxide respectively.

AB - Alk-4-enesulphonyl chlorides and alk-5-enesulphonyl chlorides cyclise under free radical conditions mainly in the endo mode to give tetrahydrothiopyran-1,1-dioxide and thiepane- 1,1-dioxide respectively.

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U2 - 10.1016/S0040-4039(00)97084-9

DO - 10.1016/S0040-4039(00)97084-9

M3 - Article

AN - SCOPUS:0025134917

SN - 0040-4039

VL - 31

SP - 6433

EP - 6436

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 44

ER -

Regioselectivity in the formation of cyclic sulphones from 4- and 5-alkenesulphonyl chlorides

Abstract

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