Redox mediation enabled by immobilised centres in the pores of a metal-organic framework grown by liquid phase epitaxy

Andre Dragaesser; Osama Shekhah; Olexandra Zybaylo; Cai Shen; Manfred Buck; Christof Woell; Derck Schlettwein

doi:10.1039/c1cc16580a

Redox mediation enabled by immobilised centres in the pores of a metal-organic framework grown by liquid phase epitaxy

Andre Dragaesser, Osama Shekhah, Olexandra Zybaylo, Cai Shen, Manfred Buck, Christof Woell, Derck Schlettwein

Research output: Contribution to journal › Article › peer-review

Abstract

A layer of a metal-organic framework (SURMOF) was prepared on a thiol monolayer on Au. Charge transport across the insulating membrane could be established by using ferrocene as an immobilised redox mediator. Reversibility of the immobilisation and its role in the electrode kinetics are discussed.

Original language	English
Pages (from-to)	663-665
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	5
DOIs	https://doi.org/10.1039/c1cc16580a
Publication status	Published - 2012

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10.1039/c1cc16580a

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title = "Redox mediation enabled by immobilised centres in the pores of a metal-organic framework grown by liquid phase epitaxy",

abstract = "A layer of a metal-organic framework (SURMOF) was prepared on a thiol monolayer on Au. Charge transport across the insulating membrane could be established by using ferrocene as an immobilised redox mediator. Reversibility of the immobilisation and its role in the electrode kinetics are discussed.",

author = "Andre Dragaesser and Osama Shekhah and Olexandra Zybaylo and Cai Shen and Manfred Buck and Christof Woell and Derck Schlettwein",

year = "2012",

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T1 - Redox mediation enabled by immobilised centres in the pores of a metal-organic framework grown by liquid phase epitaxy

AU - Dragaesser, Andre

AU - Shekhah, Osama

AU - Zybaylo, Olexandra

AU - Shen, Cai

AU - Buck, Manfred

AU - Woell, Christof

AU - Schlettwein, Derck

PY - 2012

Y1 - 2012

N2 - A layer of a metal-organic framework (SURMOF) was prepared on a thiol monolayer on Au. Charge transport across the insulating membrane could be established by using ferrocene as an immobilised redox mediator. Reversibility of the immobilisation and its role in the electrode kinetics are discussed.

AB - A layer of a metal-organic framework (SURMOF) was prepared on a thiol monolayer on Au. Charge transport across the insulating membrane could be established by using ferrocene as an immobilised redox mediator. Reversibility of the immobilisation and its role in the electrode kinetics are discussed.

UR - https://www.scopus.com/pages/publications/83455236786

U2 - 10.1039/c1cc16580a

DO - 10.1039/c1cc16580a

M3 - Article

SN - 1359-7345

VL - 48

SP - 663

EP - 665

JO - Chemical Communications

JF - Chemical Communications

IS - 5

ER -

Redox mediation enabled by immobilised centres in the pores of a metal-organic framework grown by liquid phase epitaxy

Abstract

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