Recognition-Induced Facilitation of a Disfavoured Diels-Alder Cycloaddition

R Bennes; Douglas Philp; N Spencer; BM Kariuki; KDM Harris

Recognition-Induced Facilitation of a Disfavoured Diels-Alder Cycloaddition

R Bennes, Douglas Philp, N Spencer, BM Kariuki, KDM Harris

Research output: Other contribution

Abstract

[GRAPHICS]

The rational design of a system which is capable of accelerating and facilitating a thermodynamically disfavored Diets-Alder cycloaddition between a furan and a maleimide is presented. The origins of the acceleration and facilitation of the cycloaddition reaction are traced by kinetic studies-allied to results from H-1 NMR spectroscopy and X-ray crystallography-to the formation of strong intramolecular hydrogen bonds in the cycloadduct.

Original language	English
Volume	1
Publication status	Published - 7 Oct 1999

Keywords

INTRAMOLECULAR REACTIONS
SYNTHETIC APPLICATIONS
CATALYSIS
ACCELERATION
ENERGETICS
CHEMISTRY
STATES

Cite this

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title = "Recognition-Induced Facilitation of a Disfavoured Diels-Alder Cycloaddition",

abstract = "[GRAPHICS]The rational design of a system which is capable of accelerating and facilitating a thermodynamically disfavored Diets-Alder cycloaddition between a furan and a maleimide is presented. The origins of the acceleration and facilitation of the cycloaddition reaction are traced by kinetic studies-allied to results from H-1 NMR spectroscopy and X-ray crystallography-to the formation of strong intramolecular hydrogen bonds in the cycloadduct.",

keywords = "INTRAMOLECULAR REACTIONS, SYNTHETIC APPLICATIONS, CATALYSIS, ACCELERATION, ENERGETICS, CHEMISTRY, STATES",

author = "R Bennes and Douglas Philp and N Spencer and BM Kariuki and KDM Harris",

note = "Org Lett",

year = "1999",

month = oct,

day = "7",

language = "English",

volume = "1",

type = "Other",

}

TY - GEN

T1 - Recognition-Induced Facilitation of a Disfavoured Diels-Alder Cycloaddition

AU - Bennes, R

AU - Philp, Douglas

AU - Spencer, N

AU - Kariuki, BM

AU - Harris, KDM

N1 - Org Lett

PY - 1999/10/7

Y1 - 1999/10/7

N2 - [GRAPHICS]The rational design of a system which is capable of accelerating and facilitating a thermodynamically disfavored Diets-Alder cycloaddition between a furan and a maleimide is presented. The origins of the acceleration and facilitation of the cycloaddition reaction are traced by kinetic studies-allied to results from H-1 NMR spectroscopy and X-ray crystallography-to the formation of strong intramolecular hydrogen bonds in the cycloadduct.

AB - [GRAPHICS]The rational design of a system which is capable of accelerating and facilitating a thermodynamically disfavored Diets-Alder cycloaddition between a furan and a maleimide is presented. The origins of the acceleration and facilitation of the cycloaddition reaction are traced by kinetic studies-allied to results from H-1 NMR spectroscopy and X-ray crystallography-to the formation of strong intramolecular hydrogen bonds in the cycloadduct.

KW - INTRAMOLECULAR REACTIONS

KW - SYNTHETIC APPLICATIONS

KW - CATALYSIS

KW - ACCELERATION

KW - ENERGETICS

KW - CHEMISTRY

KW - STATES

M3 - Other contribution

VL - 1

ER -

Recognition-Induced Facilitation of a Disfavoured Diels-Alder Cycloaddition

Abstract

Keywords

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