Reactivity of Woollins’ Reagent toward 2-en-1-imines (Schiff bases): a facile approach to synthesize new selenium-phosphorus-nitrogen heterocycles

Guoxiong Hua, David B Cordes, Alexandra Slawin, J. Derek Woollins

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)
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Abstract

Woollins’ Reagent serves as a reductive cycloaddition reagent, reacting with 2‐en‐1‐imines containing a conjugated C=C bond group (Schiff bases) leading to a series of four‐, five‐, six‐membered 1,2‐azaphospholidines incorporating one or two N‐P=Se linkages. Ten single crystal X‐ray structures confirming the formation of these small N‐P‐Se heterocycles are reported.
Original languageEnglish
Pages (from-to)4682-4689
JournalEuropean Journal of Inorganic Chemistry
Volume2019
Issue number43
Early online date4 Nov 2019
DOIs
Publication statusPublished - 24 Nov 2019

Keywords

  • Selenium
  • Woollins’ Reagent
  • Synthesis
  • Phosphorus-selenium-nitrogen hetrocycles
  • X-ray structure

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