Reactivity of a N-heterocyclic carbene, 1,3-di-(1-adamantyl) imidazol 2-ylidene, with a pseudo-acid: structural characterization of Claisen condensation adduct

G A  Grasa; R  Singh; N M  Scott; E D  Stevens; Steven Patrick Nolan

doi:10.1039/b410986d

Reactivity of a N-heterocyclic carbene, 1,3-di-(1-adamantyl) imidazol 2-ylidene, with a pseudo-acid: structural characterization of Claisen condensation adduct

G A Grasa, R Singh, N M Scott, E D Stevens, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

The reactivity of a N-heterocyclic carbene (NHC) with a pseudo-acid (ester in this case) is described. The product results from an unusual C-H bond activation. The structure of the product has been established by a single crystal diffraction study.

Original language	English
Pages (from-to)	2890-2891
Number of pages	2
Journal	Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/b410986d
Publication status	Published - 2004

Keywords

NUCLEOPHILIC CARBENE
TRANSESTERIFICATION/ACYLATION REACTIONS
STABLE CARBENES
LIVING POLYMERIZATION
CATALYSTS
COMPLEXES
LIGANDS
BEARING

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abstract = "The reactivity of a N-heterocyclic carbene (NHC) with a pseudo-acid (ester in this case) is described. The product results from an unusual C-H bond activation. The structure of the product has been established by a single crystal diffraction study.",

keywords = "NUCLEOPHILIC CARBENE, TRANSESTERIFICATION/ACYLATION REACTIONS, STABLE CARBENES, LIVING POLYMERIZATION, CATALYSTS, COMPLEXES, LIGANDS, BEARING",

author = "Grasa, {G A} and R Singh and Scott, {N M} and Stevens, {E D} and Nolan, {Steven Patrick}",

year = "2004",

doi = "10.1039/b410986d",

language = "English",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Reactivity of a N-heterocyclic carbene, 1,3-di-(1-adamantyl) imidazol 2-ylidene, with a pseudo-acid: structural characterization of Claisen condensation adduct

AU - Grasa, G A

AU - Singh, R

AU - Scott, N M

AU - Stevens, E D

AU - Nolan, Steven Patrick

PY - 2004

Y1 - 2004

N2 - The reactivity of a N-heterocyclic carbene (NHC) with a pseudo-acid (ester in this case) is described. The product results from an unusual C-H bond activation. The structure of the product has been established by a single crystal diffraction study.

AB - The reactivity of a N-heterocyclic carbene (NHC) with a pseudo-acid (ester in this case) is described. The product results from an unusual C-H bond activation. The structure of the product has been established by a single crystal diffraction study.

KW - NUCLEOPHILIC CARBENE

KW - TRANSESTERIFICATION/ACYLATION REACTIONS

KW - STABLE CARBENES

KW - LIVING POLYMERIZATION

KW - CATALYSTS

KW - COMPLEXES

KW - LIGANDS

KW - BEARING

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U2 - 10.1039/b410986d

DO - 10.1039/b410986d

M3 - Article

SN - 1359-7345

SP - 2890

EP - 2891

JO - Chemical Communications

JF - Chemical Communications

IS - 24

ER -

Reactivity of a N-heterocyclic carbene, 1,3-di-(1-adamantyl) imidazol 2-ylidene, with a pseudo-acid: structural characterization of Claisen condensation adduct

Abstract

Keywords

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