REACTIONS OF 1,3-EPITHIONAPHTHO[1,8-CD][1,2-LAMBDA-5,6-LAMBDA-5]THIADIPHOSPHININE-1,3-DITHIONE - THE PREPARATION AND X-RAY STRUCTURE OF NPP(S)(SME)SP(S)(OME), THE 1ST C3P2S RING

M E ELEFTHERIOU, J NOVOSAD, D J WILLIAMS, J D WOOLLINS

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

NpP2S4 1 (Np = C10H6, naphthalene-1,8-diyl) reacts with carbonyl groups to give thiocarbonyls whilst refluxing 1 in methanol results in cleavage of one of the P-S-P bridges and formation of the new heterocycle 3 which contains a C3P2S ring with the phosphorus atoms asymmetrically substituted by methoxy and thiomethoxy groups.

Original languageEnglish
Pages (from-to)116-117
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number2
Publication statusPublished - 15 Jan 1991

Fingerprint

Dive into the research topics of 'REACTIONS OF 1,3-EPITHIONAPHTHO[1,8-CD][1,2-LAMBDA-5,6-LAMBDA-5]THIADIPHOSPHININE-1,3-DITHIONE - THE PREPARATION AND X-RAY STRUCTURE OF NPP(S)(SME)SP(S)(OME), THE 1ST C3P2S RING'. Together they form a unique fingerprint.

Cite this