TY - GEN
T1 - Reaction of 2,4-(Naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane 2,4-with Bases and Acids
AU - Fei, Z
AU - Slawin, Alexandra Martha Zoya
AU - Woollins, John Derek
N1 - Phosphorus, Sulf.Silicon
PY - 2001
Y1 - 2001
N2 - The compound 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide 1 reacts with different bases 2a-2d HNR(HNR = N,N,N',N'-tetramethyl-guanidine, morpholine, pyrrolidine or NH3) to give the corresponding ammonium salts of 3a-3d. The reaction of 1 with Et(3)N(.)3HF lead to the formation of 4a. The new compounds formed from the reactions have been studied spectroscopically and by X-ray crystallography.
AB - The compound 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide 1 reacts with different bases 2a-2d HNR(HNR = N,N,N',N'-tetramethyl-guanidine, morpholine, pyrrolidine or NH3) to give the corresponding ammonium salts of 3a-3d. The reaction of 1 with Et(3)N(.)3HF lead to the formation of 4a. The new compounds formed from the reactions have been studied spectroscopically and by X-ray crystallography.
KW - P-S bond
KW - NMR
KW - X-ray crystal structure
UR - http://www.scopus.com/inward/record.url?scp=0035650022&partnerID=8YFLogxK
M3 - Other contribution
VL - 168
ER -