Rational design of diphosphorus ligands - a route to superior catalysts

Jason A. Gillespie; Deborah L. Dodds; Paul C. J. Kamer

doi:10.1039/b913778e

Rational design of diphosphorus ligands - a route to superior catalysts

Jason A. Gillespie, Deborah L. Dodds, Paul C. J. Kamer^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The development of catalytic chemical conversions owes its success to the procreation of ligand variety and parameter quanti. cation. Rational ligand design can provide a powerful means to tune transition metal reactivity and reaction selectivity. In this review an attempt is made to describe the quanti. cation of ligand parameters and to present examples of successful ligand design in several academically and industrially important catalytic systems.

Original language	English
Pages (from-to)	2751-2764
Number of pages	14
Journal	Dalton Transactions
Volume	39
Issue number	11
DOIs	https://doi.org/10.1039/b913778e
Publication status	Published - 2010

Keywords

FORMING REDUCTIVE ELIMINATION
ASYMMETRIC ALLYLIC ALKYLATION
PHOSPHINE-PHOSPHITE LIGANDS
ARYL HALIDE AMINATION
NATURAL BITE ANGLE
ORGANOMETALLIC CHEMISTRY
HOMOGENEOUS CATALYSIS
PALLADIUM COMPLEXES
PHOSPHORUS LIGANDS
ENANTIOSELECTIVE HYDROGENATION

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10.1039/b913778e

EPSRC: EFFICIENT PRODUCTION OF HIGH: Efficient production of high value added materials via selective hydroformylation
Kamer, P. C. J. (PI)
EPSRC
1/04/07 → 28/03/10
Project: Standard

Cite this

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title = "Rational design of diphosphorus ligands - a route to superior catalysts",

abstract = "The development of catalytic chemical conversions owes its success to the procreation of ligand variety and parameter quanti. cation. Rational ligand design can provide a powerful means to tune transition metal reactivity and reaction selectivity. In this review an attempt is made to describe the quanti. cation of ligand parameters and to present examples of successful ligand design in several academically and industrially important catalytic systems.",

keywords = "FORMING REDUCTIVE ELIMINATION, ASYMMETRIC ALLYLIC ALKYLATION, PHOSPHINE-PHOSPHITE LIGANDS, ARYL HALIDE AMINATION, NATURAL BITE ANGLE, ORGANOMETALLIC CHEMISTRY, HOMOGENEOUS CATALYSIS, PALLADIUM COMPLEXES, PHOSPHORUS LIGANDS, ENANTIOSELECTIVE HYDROGENATION",

author = "Gillespie, {Jason A.} and Dodds, {Deborah L.} and Kamer, {Paul C. J.}",

year = "2010",

doi = "10.1039/b913778e",

language = "English",

volume = "39",

pages = "2751--2764",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "ROYAL SOC CHEMISTRY",

number = "11",

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TY - JOUR

T1 - Rational design of diphosphorus ligands - a route to superior catalysts

AU - Gillespie, Jason A.

AU - Dodds, Deborah L.

AU - Kamer, Paul C. J.

PY - 2010

Y1 - 2010

N2 - The development of catalytic chemical conversions owes its success to the procreation of ligand variety and parameter quanti. cation. Rational ligand design can provide a powerful means to tune transition metal reactivity and reaction selectivity. In this review an attempt is made to describe the quanti. cation of ligand parameters and to present examples of successful ligand design in several academically and industrially important catalytic systems.

AB - The development of catalytic chemical conversions owes its success to the procreation of ligand variety and parameter quanti. cation. Rational ligand design can provide a powerful means to tune transition metal reactivity and reaction selectivity. In this review an attempt is made to describe the quanti. cation of ligand parameters and to present examples of successful ligand design in several academically and industrially important catalytic systems.

KW - FORMING REDUCTIVE ELIMINATION

KW - ASYMMETRIC ALLYLIC ALKYLATION

KW - PHOSPHINE-PHOSPHITE LIGANDS

KW - ARYL HALIDE AMINATION

KW - NATURAL BITE ANGLE

KW - ORGANOMETALLIC CHEMISTRY

KW - HOMOGENEOUS CATALYSIS

KW - PALLADIUM COMPLEXES

KW - PHOSPHORUS LIGANDS

KW - ENANTIOSELECTIVE HYDROGENATION

U2 - 10.1039/b913778e

DO - 10.1039/b913778e

M3 - Article

SN - 1477-9226

VL - 39

SP - 2751

EP - 2764

JO - Dalton Transactions

JF - Dalton Transactions

IS - 11

ER -

Rational design of diphosphorus ligands - a route to superior catalysts

Abstract

Keywords

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Projects

EPSRC: EFFICIENT PRODUCTION OF HIGH: Efficient production of high value added materials via selective hydroformylation

Cite this