Rate of combination of trichloromethyl radicals

J. M. Tedder; J. C. Walton

doi:10.1039/tf9676302464

Rate of combination of trichloromethyl radicals

J. M. Tedder^*, J. C. Walton

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The rotating sector technique has been applied to a study of the photochemical addition of bromotrichloromethane to ethylene in the gas phase.¹ From these data the rate constant of trichloromethyl radical combination has been determined: CCl₃·+CCl₃· →C₂Cl₆, k₆ = 10^10.9 1. mole^-1 sec^-1 independent of temperature in the range 77-173°C.

Original language	English
Pages (from-to)	2464-2469
Number of pages	6
Journal	Transactions of the Faraday Society
Volume	63
DOIs	https://doi.org/10.1039/tf9676302464
Publication status	Published - 1 Jan 1967

Access to Document

10.1039/tf9676302464

Cite this

@article{3dcdb184fd4443f399f640da9ca9243e,

title = "Rate of combination of trichloromethyl radicals",

abstract = "The rotating sector technique has been applied to a study of the photochemical addition of bromotrichloromethane to ethylene in the gas phase.1 From these data the rate constant of trichloromethyl radical combination has been determined: CCl3·+CCl3· →C2Cl6, k6 = 1010.9 1. mole-1 sec-1 independent of temperature in the range 77-173°C.",

author = "Tedder, {J. M.} and Walton, {J. C.}",

year = "1967",

month = jan,

day = "1",

doi = "10.1039/tf9676302464",

language = "English",

volume = "63",

pages = "2464--2469",

journal = "Transactions of the Faraday Society",

issn = "0014-7672",

publisher = "Faraday Division of the Chemical Society",

}

TY - JOUR

T1 - Rate of combination of trichloromethyl radicals

AU - Tedder, J. M.

AU - Walton, J. C.

PY - 1967/1/1

Y1 - 1967/1/1

N2 - The rotating sector technique has been applied to a study of the photochemical addition of bromotrichloromethane to ethylene in the gas phase.1 From these data the rate constant of trichloromethyl radical combination has been determined: CCl3·+CCl3· →C2Cl6, k6 = 1010.9 1. mole-1 sec-1 independent of temperature in the range 77-173°C.

AB - The rotating sector technique has been applied to a study of the photochemical addition of bromotrichloromethane to ethylene in the gas phase.1 From these data the rate constant of trichloromethyl radical combination has been determined: CCl3·+CCl3· →C2Cl6, k6 = 1010.9 1. mole-1 sec-1 independent of temperature in the range 77-173°C.

UR - http://www.scopus.com/inward/record.url?scp=37049130723&partnerID=8YFLogxK

U2 - 10.1039/tf9676302464

DO - 10.1039/tf9676302464

M3 - Article

AN - SCOPUS:37049130723

SN - 0014-7672

VL - 63

SP - 2464

EP - 2469

JO - Transactions of the Faraday Society

JF - Transactions of the Faraday Society

ER -

Rate of combination of trichloromethyl radicals

Abstract

Access to Document

Other files and links

Fingerprint

Cite this