Raman scattering with strongly coupled vibron-polaritons

Artem Strashko, Jonathan Keeling

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24 Citations (Scopus)
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Abstract

Strong coupling between cavity photons and molecular vibrations can lead to the formation of vibron-polaritons. In a recent experiment with PVAc molecules in a metal-metal microcavity [A.Shalabney et al., Ang.Chem.Int.Ed. 54 7971 (2015)], such a coupling was observed to enhance the Raman scattering probability by several orders of magnitude. Inspired by this, we theoretically analyze the effect of strong photon-vibron coupling on the Raman scattering amplitude of organic molecules. This problem has recently been addressed in [J.del Pino, J.Feist and F.J.Garcia-Vidal; J.Phys.Chem.C 119 29132 (2015)] using exact numerics for a small number of molecules. In this paper we derive compact analytic results for any number of molecules, also including the ultra-strong coupling regime. Our calculations predict a division of the Raman signal into upper and lower polariton modes,with some enhancement to the lower polariton Raman amplitude due to the mode softening under strong coupling.
Original languageEnglish
Article number023843
Number of pages10
JournalPhysical Review. A, Atomic, molecular, and optical physics
Volume94
Issue number2
Early online date25 Aug 2016
DOIs
Publication statusPublished - Aug 2016

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