Radical rearrangements of bicyclo[2.2.0]hexane: Homolytic substitution of a cyclobutane ring

John C. Walton

doi:10.1039/C39870001252

Radical rearrangements of bicyclo[2.2.0]hexane: Homolytic substitution of a cyclobutane ring

John C. Walton^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Bromine atoms react with bicyclo[2.2.0]hexane in an S_H2 reaction at the bridgehead carbon atoms; the bicyclo[2.2.0]hex-2-yl radical rearranges by β-scission of the inter-ring bond.

Original language	English
Pages (from-to)	1252-1254
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/C39870001252
Publication status	Published - 1 Dec 1987

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@article{4756c3add589405084f516a20ce1212b,

title = "Radical rearrangements of bicyclo[2.2.0]hexane: Homolytic substitution of a cyclobutane ring",

abstract = "Bromine atoms react with bicyclo[2.2.0]hexane in an SH2 reaction at the bridgehead carbon atoms; the bicyclo[2.2.0]hex-2-yl radical rearranges by β-scission of the inter-ring bond.",

author = "Walton, \{John C.\}",

year = "1987",

month = dec,

day = "1",

doi = "10.1039/C39870001252",

language = "English",

pages = "1252--1254",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "16",

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T1 - Radical rearrangements of bicyclo[2.2.0]hexane

T2 - Homolytic substitution of a cyclobutane ring

AU - Walton, John C.

PY - 1987/12/1

Y1 - 1987/12/1

N2 - Bromine atoms react with bicyclo[2.2.0]hexane in an SH2 reaction at the bridgehead carbon atoms; the bicyclo[2.2.0]hex-2-yl radical rearranges by β-scission of the inter-ring bond.

AB - Bromine atoms react with bicyclo[2.2.0]hexane in an SH2 reaction at the bridgehead carbon atoms; the bicyclo[2.2.0]hex-2-yl radical rearranges by β-scission of the inter-ring bond.

UR - https://www.scopus.com/pages/publications/37049069289

U2 - 10.1039/C39870001252

DO - 10.1039/C39870001252

M3 - Article

AN - SCOPUS:37049069289

SN - 0022-4936

SP - 1252

EP - 1254

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 16

ER -

Radical rearrangements of bicyclo[2.2.0]hexane: Homolytic substitution of a cyclobutane ring

Abstract

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