Radical-carbanion cyclo-coupling in armed aromatics: overriding steric hindrance to ring closure

John Christopher Walton, M. D. Roydhouse

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

omega-(2-Halophenyl)alkyl-2-oxazolines were prepared and reacted via base promoted intramolecular coupling of radical with carbanionic centres to yield 1-phenyl-1-oxazolino-indan and -tetralin derivatives containing quaternary C-atoms.

Original languageEnglish
Pages (from-to)4453-4455
Number of pages3
JournalChemical Communications
DOIs
Publication statusPublished - 2005

Keywords

  • NUCLEOPHILIC-SUBSTITUTION
  • S(RN)1 MECHANISM
  • ANALOGS
  • CHLORANILINES
  • CYCLIZATIONS
  • DERIVATIVES
  • DIANIONS
  • NITROGEN
  • ANIONS

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