rac-1-phenylethylammonium carboxymethylphosphonate(1-): hydrogen-bonded anion sheets with pendent cations

D E  Turkington; G  Ferguson; A J  Lough; C  Glidewell

doi:10.1107/S0108270104000939

rac-1-phenylethylammonium carboxymethylphosphonate(1-): hydrogen-bonded anion sheets with pendent cations

D E Turkington, G Ferguson, A J Lough, C Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, C8H12N+.C2H4O5P-, the anions are linked by two O-H...O hydrogen bonds [H...O both 1.75 Angstrom, O...O = 2.5781 (15) and 2.5834 (15) Angstrom, and O-H...O = 169 and 176degrees] into sheets built from alternating R-2(2)(8) and R-6(6)(32) rings. Each cation is linked to an anion sheet by three N-H...O hydrogen bonds [H...O = 1.88-2.04 Angstrom, N...O = 2.7603 (16)-2.9334 (17) Angstrom and N-H...O = 162-166degrees], such that all the cations pendent from one face of the sheet are of the R configuration, while all those pendent from the opposite face are of the S configuration.

Original language	English
Number of pages	3
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	60
DOIs	https://doi.org/10.1107/S0108270104000939
Publication status	Published - Mar 2004

Keywords

PHOSPHONOACETIC ACID
SALTS

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@article{286fe54051aa4ffab8de41023e1b8b25,

title = "rac-1-phenylethylammonium carboxymethylphosphonate(1-): hydrogen-bonded anion sheets with pendent cations",

abstract = "In the title compound, C8H12N+.C2H4O5P-, the anions are linked by two O-H...O hydrogen bonds [H...O both 1.75 Angstrom, O...O = 2.5781 (15) and 2.5834 (15) Angstrom, and O-H...O = 169 and 176degrees] into sheets built from alternating R-2(2)(8) and R-6(6)(32) rings. Each cation is linked to an anion sheet by three N-H...O hydrogen bonds [H...O = 1.88-2.04 Angstrom, N...O = 2.7603 (16)-2.9334 (17) Angstrom and N-H...O = 162-166degrees], such that all the cations pendent from one face of the sheet are of the R configuration, while all those pendent from the opposite face are of the S configuration.",

keywords = "PHOSPHONOACETIC ACID, SALTS",

author = "Turkington, \{D E\} and G Ferguson and Lough, \{A J\} and C Glidewell",

year = "2004",

month = mar,

doi = "10.1107/S0108270104000939",

language = "English",

volume = "60",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

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TY - JOUR

T1 - rac-1-phenylethylammonium carboxymethylphosphonate(1-): hydrogen-bonded anion sheets with pendent cations

AU - Turkington, D E

AU - Ferguson, G

AU - Lough, A J

AU - Glidewell, C

PY - 2004/3

Y1 - 2004/3

N2 - In the title compound, C8H12N+.C2H4O5P-, the anions are linked by two O-H...O hydrogen bonds [H...O both 1.75 Angstrom, O...O = 2.5781 (15) and 2.5834 (15) Angstrom, and O-H...O = 169 and 176degrees] into sheets built from alternating R-2(2)(8) and R-6(6)(32) rings. Each cation is linked to an anion sheet by three N-H...O hydrogen bonds [H...O = 1.88-2.04 Angstrom, N...O = 2.7603 (16)-2.9334 (17) Angstrom and N-H...O = 162-166degrees], such that all the cations pendent from one face of the sheet are of the R configuration, while all those pendent from the opposite face are of the S configuration.

AB - In the title compound, C8H12N+.C2H4O5P-, the anions are linked by two O-H...O hydrogen bonds [H...O both 1.75 Angstrom, O...O = 2.5781 (15) and 2.5834 (15) Angstrom, and O-H...O = 169 and 176degrees] into sheets built from alternating R-2(2)(8) and R-6(6)(32) rings. Each cation is linked to an anion sheet by three N-H...O hydrogen bonds [H...O = 1.88-2.04 Angstrom, N...O = 2.7603 (16)-2.9334 (17) Angstrom and N-H...O = 162-166degrees], such that all the cations pendent from one face of the sheet are of the R configuration, while all those pendent from the opposite face are of the S configuration.

KW - PHOSPHONOACETIC ACID

KW - SALTS

UR - https://www.scopus.com/pages/publications/1842785406

U2 - 10.1107/S0108270104000939

DO - 10.1107/S0108270104000939

M3 - Article

SN - 1600-5759

SN - 0108-2701

VL - 60

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

rac-1-phenylethylammonium carboxymethylphosphonate(1-): hydrogen-bonded anion sheets with pendent cations

Abstract

Keywords

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