Pressure-induced chemistry for the 2D to 3D transformation of zeolites

Michal Mazur; Angel M. Arévalo-López; Paul S. Wheatley; Giulia P. M. Bignami; Sharon E. Ashbrook; Ángel Morales-García; Petr Nachtigall; J. Paul Attfield; Jiři  Čejka; Russell E. Morris

doi:10.1039/C7TA09248B

Pressure-induced chemistry for the 2D to 3D transformation of zeolites

Michal Mazur, Angel M. Arévalo-López, Paul S. Wheatley, Giulia P. M. Bignami, Sharon E. Ashbrook, Ángel Morales-García, Petr Nachtigall, J. Paul Attfield, Jiři Čejka, Russell E. Morris

Research output: Contribution to journal › Article › peer-review

Abstract

ADOR, an unconventional synthesis strategy based on a four-step mechanism: assembly, disassembly, organization, and reassembly, has opened new possibilities in zeolite chemistry. The ADOR approach led to the discovery of the IPC family of materials with tuneable porosity. Here we present the first pressure-induced ADOR transformation of 2D zeolite precursor IPC-1P into fully crystalline 3D zeolite IPC-2 (OKO topology) using a Walker-type multianvil apparatus under a pressure of 1 GPa at 200 °C. Surprisingly, the high-pressure material is of lower density (higher porosity) than the product obtained from simply calcining the IPC-1P precursor at high temperature, which produces IPC-4 (PCR topology). The sample was characterized by PXRD, ²⁹Si MAS NMR, SEM, and HRTEM. Theoretical calculations suggest that high pressure can lead to the preparation of other ADOR zeolites that have not yet been prepared.

Original language	English
Pages (from-to)	5255-5259
Journal	Journal of Materials Chemistry
Volume	6
Issue number	13
Early online date	20 Nov 2017
DOIs	https://doi.org/10.1039/C7TA09248B
Publication status	Published - 7 Apr 2018

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Morris_2017_JMCA_Pressure-induced_AAM
© 2017 the Authors. This work has been made available online in accordance with the publisher’s policies. This is the author created accepted version manuscript following peer review and as such may differ slightly from the final published version. The final published version of this work is available at https://doi.org/ 10.1039/C7TA09248B
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SuppInfo_Pressure-induced_JMCAAccepted author manuscript, 591 KB

Nanoparticle: Nanoparticle Approaches to Zeolitic Catalysts
Morris, R. E. (PI)
EPSRC
15/01/14 → 2/08/15
Project: Standard
Assembly Disassembly Reassembly: Assembly disassembly reassembly - New routes to extended structures and their impact
Morris, R. E. (PI)
EPSRC
1/08/13 → 31/07/18
Project: Fellowship

Pressure-induced chemistry for the 2D to 3D transformation of zeolites (dataset)
Mazur, M. (Creator), Arévalo-López, A. M. (Creator), Wheatley, P. S. (Creator), Bignami, G. P. M. (Creator), Ashbrook, S. E. M. (Creator), Morales-García, Á. (Creator), Nachtigall, P. (Creator), Attfield, J. P. (Creator), Čejka, J. (Creator) & Morris, R. E. (Creator), University of St Andrews, 29 Aug 2019
DOI: 10.17630/8fb0373c-cd0f-4e28-8863-e0bfb7e06539
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title = "Pressure-induced chemistry for the 2D to 3D transformation of zeolites",

abstract = "ADOR, an unconventional synthesis strategy based on a four-step mechanism: assembly, disassembly, organization, and reassembly, has opened new possibilities in zeolite chemistry. The ADOR approach led to the discovery of the IPC family of materials with tuneable porosity. Here we present the first pressure-induced ADOR transformation of 2D zeolite precursor IPC-1P into fully crystalline 3D zeolite IPC-2 (OKO topology) using a Walker-type multianvil apparatus under a pressure of 1 GPa at 200 °C. Surprisingly, the high-pressure material is of lower density (higher porosity) than the product obtained from simply calcining the IPC-1P precursor at high temperature, which produces IPC-4 (PCR topology). The sample was characterized by PXRD, 29Si MAS NMR, SEM, and HRTEM. Theoretical calculations suggest that high pressure can lead to the preparation of other ADOR zeolites that have not yet been prepared.",

author = "Michal Mazur and Ar{\'e}valo-L{\'o}pez, {Angel M.} and Wheatley, {Paul S.} and Bignami, {Giulia P. M.} and Ashbrook, {Sharon E.} and {\'A}ngel Morales-Garc{\'i}a and Petr Nachtigall and Attfield, {J. Paul} and Ji{\v r}i {\v C}ejka and Morris, {Russell E.}",

note = "M.M., P.S.W., G.P.M.B., S.E.A., and R.E.M. thank the EPSRC (grants: EP/K025112/1, EP/L014475/1, and EP/ M506631/1) for funding. M.M., P.N., J.{\v C}. and R.E.M. would like to acknowledge OP VVV {"}Excellent Research Teams{"}, project No. CZ.02.1.01/0.0/0.0/15_003/0000417 - CUCAM. J.{\v C}. and P.N. acknowledge the Czech Science Foundation (P106/12/G015) for the financial support of this research. J.P.A. acknowledges EPSRC support for the high pressure work.",

year = "2018",

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doi = "10.1039/C7TA09248B",

language = "English",

volume = "6",

pages = "5255--5259",

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T1 - Pressure-induced chemistry for the 2D to 3D transformation of zeolites

AU - Mazur, Michal

AU - Arévalo-López, Angel M.

AU - Wheatley, Paul S.

AU - Bignami, Giulia P. M.

AU - Ashbrook, Sharon E.

AU - Morales-García, Ángel

AU - Nachtigall, Petr

AU - Attfield, J. Paul

AU - Čejka, Jiři

AU - Morris, Russell E.

N1 - M.M., P.S.W., G.P.M.B., S.E.A., and R.E.M. thank the EPSRC (grants: EP/K025112/1, EP/L014475/1, and EP/ M506631/1) for funding. M.M., P.N., J.Č. and R.E.M. would like to acknowledge OP VVV "Excellent Research Teams", project No. CZ.02.1.01/0.0/0.0/15_003/0000417 - CUCAM. J.Č. and P.N. acknowledge the Czech Science Foundation (P106/12/G015) for the financial support of this research. J.P.A. acknowledges EPSRC support for the high pressure work.

PY - 2018/4/7

Y1 - 2018/4/7

N2 - ADOR, an unconventional synthesis strategy based on a four-step mechanism: assembly, disassembly, organization, and reassembly, has opened new possibilities in zeolite chemistry. The ADOR approach led to the discovery of the IPC family of materials with tuneable porosity. Here we present the first pressure-induced ADOR transformation of 2D zeolite precursor IPC-1P into fully crystalline 3D zeolite IPC-2 (OKO topology) using a Walker-type multianvil apparatus under a pressure of 1 GPa at 200 °C. Surprisingly, the high-pressure material is of lower density (higher porosity) than the product obtained from simply calcining the IPC-1P precursor at high temperature, which produces IPC-4 (PCR topology). The sample was characterized by PXRD, 29Si MAS NMR, SEM, and HRTEM. Theoretical calculations suggest that high pressure can lead to the preparation of other ADOR zeolites that have not yet been prepared.

AB - ADOR, an unconventional synthesis strategy based on a four-step mechanism: assembly, disassembly, organization, and reassembly, has opened new possibilities in zeolite chemistry. The ADOR approach led to the discovery of the IPC family of materials with tuneable porosity. Here we present the first pressure-induced ADOR transformation of 2D zeolite precursor IPC-1P into fully crystalline 3D zeolite IPC-2 (OKO topology) using a Walker-type multianvil apparatus under a pressure of 1 GPa at 200 °C. Surprisingly, the high-pressure material is of lower density (higher porosity) than the product obtained from simply calcining the IPC-1P precursor at high temperature, which produces IPC-4 (PCR topology). The sample was characterized by PXRD, 29Si MAS NMR, SEM, and HRTEM. Theoretical calculations suggest that high pressure can lead to the preparation of other ADOR zeolites that have not yet been prepared.

U2 - 10.1039/C7TA09248B

DO - 10.1039/C7TA09248B

M3 - Article

SN - 0959-9428

VL - 6

SP - 5255

EP - 5259

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

IS - 13

ER -

Pressure-induced chemistry for the 2D to 3D transformation of zeolites

Abstract

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Projects

Nanoparticle: Nanoparticle Approaches to Zeolitic Catalysts

Assembly Disassembly Reassembly: Assembly disassembly reassembly - New routes to extended structures and their impact

Datasets

Pressure-induced chemistry for the 2D to 3D transformation of zeolites (dataset)

Cite this