Pressure and guest-mediated pore shape modification in a small pore MOF to 1200 bar

Charles J. McMonagle, Gemma F. Turner, Isabelle Jones, David R. Allan, Mark R. Warren, Konstantin V. Kamenev, Simon Parsons, Paul A. Wright*, Stephen A. Moggach*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)
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Abstract

Guest-mediated pore-shape modification of the metal–organic framework, Sc2BDC3 upon adsorption of n-pentane and isopentane is examined from 50–1200 bar. Rotation of the BDC linker responsible for the change in pore shape occurs at much lower pressures than previously reported, with distinct adsorption behaviour observed between pentane isomers.
Original languageEnglish
Pages (from-to)11465–11598
Number of pages4
JournalChemical Communications
Volume58
Issue number82
Early online date16 Sept 2022
DOIs
Publication statusPublished - 21 Oct 2022

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