Pressure and guest-mediated pore shape modification in a small pore MOF to 1200 bar

Charles J. McMonagle; Gemma F. Turner; Isabelle Jones; David R. Allan; Mark R. Warren; Konstantin V. Kamenev; Simon Parsons; Paul A. Wright; Stephen A. Moggach

doi:10.1039/d2cc04649k

Pressure and guest-mediated pore shape modification in a small pore MOF to 1200 bar

Charles J. McMonagle, Gemma F. Turner, Isabelle Jones, David R. Allan, Mark R. Warren, Konstantin V. Kamenev, Simon Parsons, Paul A. Wright^*, Stephen A. Moggach^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Guest-mediated pore-shape modification of the metal–organic framework, Sc₂BDC₃ upon adsorption of n-pentane and isopentane is examined from 50–1200 bar. Rotation of the BDC linker responsible for the change in pore shape occurs at much lower pressures than previously reported, with distinct adsorption behaviour observed between pentane isomers.

Original language	English
Pages (from-to)	11465–11598
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	82
Early online date	16 Sept 2022
DOIs	https://doi.org/10.1039/d2cc04649k
Publication status	Published - 21 Oct 2022

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10.1039/d2cc04649k

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Copyright © 2022 The Author(s). This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/D2CC04649K
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CCDC 2202161 - 2202178: Experimental Crystal Structure Determination
McMonagle, C. J. (Creator), Turner, G. F. (Creator), Jones, I. (Creator), Allan, D. R. (Creator), Warren, M. R. (Creator), Kamenev, K. V. (Creator), Parsons, S. (Creator), Wright, P. A. (Creator) & Moggach, S. A. (Creator), Cambridge Crystallographic Data Centre, 2022
DOI: 10.5517/ccdc.csd.cc2cxjg9, https://dx.doi.org/10.5517/ccdc.csd.cc2cxjhb and 16 more links, https://dx.doi.org/10.5517/ccdc.csd.cc2cxjjc, https://dx.doi.org/10.5517/ccdc.csd.cc2cxjkd, https://dx.doi.org/10.5517/ccdc.csd.cc2cxjlf, https://dx.doi.org/10.5517/ccdc.csd.cc2cxjmg, https://dx.doi.org/10.5517/ccdc.csd.cc2cxjnh, https://dx.doi.org/10.5517/ccdc.csd.cc2cxjpj, https://dx.doi.org/10.5517/ccdc.csd.cc2cxjqk, https://dx.doi.org/10.5517/ccdc.csd.cc2cxjrl, https://dx.doi.org/10.5517/ccdc.csd.cc2cxjsm, https://dx.doi.org/10.5517/ccdc.csd.cc2cxjtn, https://dx.doi.org/10.5517/ccdc.csd.cc2cxjvp, https://dx.doi.org/10.5517/ccdc.csd.cc2cxjwq, https://dx.doi.org/10.5517/ccdc.csd.cc2cxjxr, https://dx.doi.org/10.5517/ccdc.csd.cc2cxjys, https://dx.doi.org/10.5517/ccdc.csd.cc2cxjzt, https://dx.doi.org/10.5517/ccdc.csd.cc2cxk0w (show fewer)
Dataset

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@article{83b540926177453e8bc4dc99004a5132,

title = "Pressure and guest-mediated pore shape modification in a small pore MOF to 1200 bar",

abstract = "Guest-mediated pore-shape modification of the metal–organic framework, Sc2BDC3 upon adsorption of n-pentane and isopentane is examined from 50–1200 bar. Rotation of the BDC linker responsible for the change in pore shape occurs at much lower pressures than previously reported, with distinct adsorption behaviour observed between pentane isomers.",

author = "McMonagle, {Charles J.} and Turner, {Gemma F.} and Isabelle Jones and Allan, {David R.} and Warren, {Mark R.} and Kamenev, {Konstantin V.} and Simon Parsons and Wright, {Paul A.} and Moggach, {Stephen A.}",

note = "The authors acknowledge Diamond Light Source, Rutherford Appleton Laboratories, for beamtime on Station I19 and the staff on beamline I19 for assistance, and for providing funding for a PhD studentship to CJM. GFT acknowledges the Australian Government for the provision of an RTP scholarship. SAM thanks the Australian Research Council (ARC) for a Future Fellowship (FT200100243).",

year = "2022",

month = oct,

day = "21",

doi = "10.1039/d2cc04649k",

language = "English",

volume = "58",

pages = "11465–11598",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "82",

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TY - JOUR

T1 - Pressure and guest-mediated pore shape modification in a small pore MOF to 1200 bar

AU - McMonagle, Charles J.

AU - Turner, Gemma F.

AU - Jones, Isabelle

AU - Allan, David R.

AU - Warren, Mark R.

AU - Kamenev, Konstantin V.

AU - Parsons, Simon

AU - Wright, Paul A.

AU - Moggach, Stephen A.

N1 - The authors acknowledge Diamond Light Source, Rutherford Appleton Laboratories, for beamtime on Station I19 and the staff on beamline I19 for assistance, and for providing funding for a PhD studentship to CJM. GFT acknowledges the Australian Government for the provision of an RTP scholarship. SAM thanks the Australian Research Council (ARC) for a Future Fellowship (FT200100243).

PY - 2022/10/21

Y1 - 2022/10/21

N2 - Guest-mediated pore-shape modification of the metal–organic framework, Sc2BDC3 upon adsorption of n-pentane and isopentane is examined from 50–1200 bar. Rotation of the BDC linker responsible for the change in pore shape occurs at much lower pressures than previously reported, with distinct adsorption behaviour observed between pentane isomers.

AB - Guest-mediated pore-shape modification of the metal–organic framework, Sc2BDC3 upon adsorption of n-pentane and isopentane is examined from 50–1200 bar. Rotation of the BDC linker responsible for the change in pore shape occurs at much lower pressures than previously reported, with distinct adsorption behaviour observed between pentane isomers.

U2 - 10.1039/d2cc04649k

DO - 10.1039/d2cc04649k

M3 - Article

SN - 1359-7345

VL - 58

SP - 11465

EP - 11598

JO - Chemical Communications

JF - Chemical Communications

IS - 82

ER -

Pressure and guest-mediated pore shape modification in a small pore MOF to 1200 bar

Abstract

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Datasets

CCDC 2202161 - 2202178: Experimental Crystal Structure Determination

Cite this