Preparation, x-ray structure and vibrational spectra of [S4N3]3Cl[SbCl6]2

S  KOHOL; D J  WILLIAMS; J D  WOOLLINS

doi:10.1080/10426509308047403

Preparation, x-ray structure and vibrational spectra of [S4N3]3Cl[SbCl6]2

S KOHOL, D J WILLIAMS, J D WOOLLINS

Research output: Contribution to journal › Article › peer-review

Abstract

The X-ray crystal structure of the title compound reveals that the planar [S4N3]+ cations surround the Cl- anion with an array of S(delta+) .... Cl- interactions. The FT Raman spectrum shows significant reduction of the nu(SS) frequency in the title compound cf. [S4N3]Cl.

Original language	English
Pages (from-to)	25-29
Number of pages	5
Journal	Phosphorus, Sulfur, and Silicon and the Related Elements
Volume	82
Issue number	1-4
DOIs	https://doi.org/10.1080/10426509308047403
Publication status	Published - 1993

Keywords

CHARGE-TRANSFER
SOLID STATE
X-RAY
ANTIMONY
CRYSTAL-STRUCTURES
NITROGEN

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10.1080/10426509308047403

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title = "Preparation, x-ray structure and vibrational spectra of [S4N3]3Cl[SbCl6]2",

abstract = "The X-ray crystal structure of the title compound reveals that the planar [S4N3]+ cations surround the Cl- anion with an array of S(delta+) .... Cl- interactions. The FT Raman spectrum shows significant reduction of the nu(SS) frequency in the title compound cf. [S4N3]Cl.",

keywords = "CHARGE-TRANSFER, SOLID STATE, X-RAY, ANTIMONY, CRYSTAL-STRUCTURES, NITROGEN",

author = "S KOHOL and WILLIAMS, {D J} and WOOLLINS, {J D}",

year = "1993",

doi = "10.1080/10426509308047403",

language = "English",

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pages = "25--29",

journal = "Phosphorus, Sulfur, and Silicon and the Related Elements",

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T1 - Preparation, x-ray structure and vibrational spectra of [S4N3]3Cl[SbCl6]2

AU - KOHOL, S

AU - WILLIAMS, D J

AU - WOOLLINS, J D

PY - 1993

Y1 - 1993

N2 - The X-ray crystal structure of the title compound reveals that the planar [S4N3]+ cations surround the Cl- anion with an array of S(delta+) .... Cl- interactions. The FT Raman spectrum shows significant reduction of the nu(SS) frequency in the title compound cf. [S4N3]Cl.

AB - The X-ray crystal structure of the title compound reveals that the planar [S4N3]+ cations surround the Cl- anion with an array of S(delta+) .... Cl- interactions. The FT Raman spectrum shows significant reduction of the nu(SS) frequency in the title compound cf. [S4N3]Cl.

KW - CHARGE-TRANSFER

KW - SOLID STATE

KW - X-RAY

KW - ANTIMONY

KW - CRYSTAL-STRUCTURES

KW - NITROGEN

U2 - 10.1080/10426509308047403

DO - 10.1080/10426509308047403

M3 - Article

SN - 1042-6507

VL - 82

SP - 25

EP - 29

JO - Phosphorus, Sulfur, and Silicon and the Related Elements

JF - Phosphorus, Sulfur, and Silicon and the Related Elements

IS - 1-4

ER -

Preparation, x-ray structure and vibrational spectra of [S4N3]3Cl[SbCl6]2

Abstract

Keywords

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