Preparation of metal–sulphur–nitrogen complexes via photochemical activation of S4N4

C W  ALLEN; P F  KELLY; J D  WOOLLINS

doi:10.1039/DT9910001343

Preparation of metal–sulphur–nitrogen complexes via photochemical activation of S4N4

C W ALLEN, P F KELLY, J D WOOLLINS

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of cis-[PtCl2(PMe2Ph)2] with S4N4, which normally only occurs at temperatures in excess of 100-degree-C, can be achieved at 0-degree-by the use of UV photolysis. Phosphorus-31 NMR studies upon reactions using S4N4-S4N-15(4) show the products to contain totally scrambled N-14/N-15 suggesting that the reaction proceeds via a reactive sulphur-nitrogen species photochemically generated from S4N4. Photolysis of S4N4 alone gives a mixture of S8, S4N2 and S7NH.

Original language	English
Pages (from-to)	1343-1345
Number of pages	3
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	5
DOIs	https://doi.org/10.1039/DT9910001343
Publication status	Published - May 1991

Keywords

M = PD
PME2PH

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10.1039/DT9910001343

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title = "Preparation of metal–sulphur–nitrogen complexes via photochemical activation of S4N4",

abstract = "Reaction of cis-[PtCl2(PMe2Ph)2] with S4N4, which normally only occurs at temperatures in excess of 100-degree-C, can be achieved at 0-degree-by the use of UV photolysis. Phosphorus-31 NMR studies upon reactions using S4N4-S4N-15(4) show the products to contain totally scrambled N-14/N-15 suggesting that the reaction proceeds via a reactive sulphur-nitrogen species photochemically generated from S4N4. Photolysis of S4N4 alone gives a mixture of S8, S4N2 and S7NH.",

keywords = "M = PD, PME2PH",

author = "ALLEN, {C W} and KELLY, {P F} and WOOLLINS, {J D}",

year = "1991",

month = may,

doi = "10.1039/DT9910001343",

language = "English",

pages = "1343--1345",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "5",

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TY - JOUR

T1 - Preparation of metal–sulphur–nitrogen complexes via photochemical activation of S4N4

AU - ALLEN, C W

AU - KELLY, P F

AU - WOOLLINS, J D

PY - 1991/5

Y1 - 1991/5

N2 - Reaction of cis-[PtCl2(PMe2Ph)2] with S4N4, which normally only occurs at temperatures in excess of 100-degree-C, can be achieved at 0-degree-by the use of UV photolysis. Phosphorus-31 NMR studies upon reactions using S4N4-S4N-15(4) show the products to contain totally scrambled N-14/N-15 suggesting that the reaction proceeds via a reactive sulphur-nitrogen species photochemically generated from S4N4. Photolysis of S4N4 alone gives a mixture of S8, S4N2 and S7NH.

AB - Reaction of cis-[PtCl2(PMe2Ph)2] with S4N4, which normally only occurs at temperatures in excess of 100-degree-C, can be achieved at 0-degree-by the use of UV photolysis. Phosphorus-31 NMR studies upon reactions using S4N4-S4N-15(4) show the products to contain totally scrambled N-14/N-15 suggesting that the reaction proceeds via a reactive sulphur-nitrogen species photochemically generated from S4N4. Photolysis of S4N4 alone gives a mixture of S8, S4N2 and S7NH.

KW - M = PD

KW - PME2PH

U2 - 10.1039/DT9910001343

DO - 10.1039/DT9910001343

M3 - Article

SN - 0300-9246

SP - 1343

EP - 1345

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 5

ER -

Preparation of metal–sulphur–nitrogen complexes via photochemical activation of S4N4

Abstract

Keywords

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