Preparation, crystal structures, conductivities and electronic structures of [et]3[NiCl4]·H2O and [et]3[AuBr4][et = bis(ethylenedithio)tetrathiafulvalene]

J D  MARTIN; E  CANADELL; J C  FITZMAURICE; A M Z  SLAWIN; D J  WILLIAMS; J D  WOOLLINS

doi:10.1039/dt9940001995

Preparation, crystal structures, conductivities and electronic structures of [et]3[NiCl4]·H2O and [et]3[AuBr4][et = bis(ethylenedithio)tetrathiafulvalene]

J D MARTIN, E CANADELL, J C FITZMAURICE, A M Z SLAWIN, D J WILLIAMS, J D WOOLLINS

Research output: Contribution to journal › Article › peer-review

Abstract

Single-crystal studies of [et]3[NiCl4].H2O and [et]3[AuBr4] [et = bis(ethylenedithio)tetrathiafulvalene] have revealed distinctly different packing motifs associated with the different anions. The nickel compound contains a sheet stack structure whilst the gold compound has a herringbone stack of et molecules. The stacking properties are discussed in the context of conductivity and band-theory calculations. The nickel compound exhibits metallic behaviour at room temperature.

Original language	English
Pages (from-to)	1995-2004
Number of pages	10
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	13
DOIs	https://doi.org/10.1039/dt9940001995
Publication status	Published - 7 Jul 1994

Keywords

BEDT-TTF SALTS
PHYSICAL-PROPERTIES
ORGANIC CONDUCTORS
BIS(ETHYLENEDITHIO)-TETRATHIAFULVALENE
SUPERCONDUCTORS
ANIONS

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10.1039/dt9940001995

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MARTIN, J. D., CANADELL, E., FITZMAURICE, J. C., SLAWIN, A. M. Z., WILLIAMS, D. J., & WOOLLINS, J. D. (1994). Preparation, crystal structures, conductivities and electronic structures of [et]3[NiCl4]·H2O and [et]3[AuBr4][et = bis(ethylenedithio)tetrathiafulvalene]. Journal of the Chemical Society, Dalton Transactions, (13), 1995-2004. https://doi.org/10.1039/dt9940001995

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title = "Preparation, crystal structures, conductivities and electronic structures of [et]3[NiCl4]·H2O and [et]3[AuBr4][et = bis(ethylenedithio)tetrathiafulvalene]",

abstract = "Single-crystal studies of [et]3[NiCl4].H2O and [et]3[AuBr4] [et = bis(ethylenedithio)tetrathiafulvalene] have revealed distinctly different packing motifs associated with the different anions. The nickel compound contains a sheet stack structure whilst the gold compound has a herringbone stack of et molecules. The stacking properties are discussed in the context of conductivity and band-theory calculations. The nickel compound exhibits metallic behaviour at room temperature.",

keywords = "BEDT-TTF SALTS, PHYSICAL-PROPERTIES, ORGANIC CONDUCTORS, BIS(ETHYLENEDITHIO)-TETRATHIAFULVALENE, SUPERCONDUCTORS, ANIONS",

author = "MARTIN, {J D} and E CANADELL and FITZMAURICE, {J C} and SLAWIN, {A M Z} and WILLIAMS, {D J} and WOOLLINS, {J D}",

year = "1994",

month = jul,

day = "7",

doi = "10.1039/dt9940001995",

language = "English",

pages = "1995--2004",

journal = "Journal of the Chemical Society, Dalton Transactions",

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Preparation, crystal structures, conductivities and electronic structures of [et]3[NiCl4]·H2O and [et]3[AuBr4][et = bis(ethylenedithio)tetrathiafulvalene]. / MARTIN, J D ; CANADELL, E ; FITZMAURICE, J C et al.
In: Journal of the Chemical Society, Dalton Transactions, No. 13, 07.07.1994, p. 1995-2004.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Preparation, crystal structures, conductivities and electronic structures of [et]3[NiCl4]·H2O and [et]3[AuBr4][et = bis(ethylenedithio)tetrathiafulvalene]

AU - MARTIN, J D

AU - CANADELL, E

AU - FITZMAURICE, J C

AU - SLAWIN, A M Z

AU - WILLIAMS, D J

AU - WOOLLINS, J D

PY - 1994/7/7

Y1 - 1994/7/7

N2 - Single-crystal studies of [et]3[NiCl4].H2O and [et]3[AuBr4] [et = bis(ethylenedithio)tetrathiafulvalene] have revealed distinctly different packing motifs associated with the different anions. The nickel compound contains a sheet stack structure whilst the gold compound has a herringbone stack of et molecules. The stacking properties are discussed in the context of conductivity and band-theory calculations. The nickel compound exhibits metallic behaviour at room temperature.

AB - Single-crystal studies of [et]3[NiCl4].H2O and [et]3[AuBr4] [et = bis(ethylenedithio)tetrathiafulvalene] have revealed distinctly different packing motifs associated with the different anions. The nickel compound contains a sheet stack structure whilst the gold compound has a herringbone stack of et molecules. The stacking properties are discussed in the context of conductivity and band-theory calculations. The nickel compound exhibits metallic behaviour at room temperature.

KW - BEDT-TTF SALTS

KW - PHYSICAL-PROPERTIES

KW - ORGANIC CONDUCTORS

KW - BIS(ETHYLENEDITHIO)-TETRATHIAFULVALENE

KW - SUPERCONDUCTORS

KW - ANIONS

U2 - 10.1039/dt9940001995

DO - 10.1039/dt9940001995

M3 - Article

SN - 0300-9246

SP - 1995

EP - 2004

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 13

ER -

Preparation, crystal structures, conductivities and electronic structures of [et]3[NiCl4]·H2O and [et]3[AuBr4][et = bis(ethylenedithio)tetrathiafulvalene]

Abstract

Keywords

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