Preparation, characterisation and use of [(n-Bu2Sn)S2N2]2 as a metathetical reagent

SM Aucott; Alexandra Martha Zoya Slawin; John Derek Woollins

Preparation, characterisation and use of [(ⁿ-Bu₂Sn)S₂N₂]₂ as a metathetical reagent

SM Aucott
, Alexandra Martha Zoya Slawin
, John Derek Woollins

Research output: Other contribution

Abstract

The dimeric compound [(eta-Bu2Sn)S2N2](2) is readily prepared by addition of eta-Bu2SnCl2 to a liquid ammonia/[S4N3][Cl] reaction mixture. Reaction of [eta-Bu2SnS2N2](2) with mono and dimeric organometallic M(III) (M=Rh, Ir) complexes bearing Cp* ligands (Cp* = 1,2,3,4,5-pentamethyicyclopentadienyl) and M(II) (M = Ru, Os) phosphine complexes containing a cis arrangement of chlorides gives compounds with MS2N2 metallacycles.

Original language	English
Volume	168
Publication status	Published - 2001

Keywords

tin
sulfur
nitrogen
metathesis
metallacycles
CRYSTAL-STRUCTURE

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@misc{f31d7c705cda4e5280542e1ee7f5354f,

title = "Preparation, characterisation and use of [(n-Bu2Sn)S2N2]2 as a metathetical reagent",

abstract = "The dimeric compound [(eta-Bu2Sn)S2N2](2) is readily prepared by addition of eta-Bu2SnCl2 to a liquid ammonia/[S4N3][Cl] reaction mixture. Reaction of [eta-Bu2SnS2N2](2) with mono and dimeric organometallic M(III) (M=Rh, Ir) complexes bearing Cp* ligands (Cp* = 1,2,3,4,5-pentamethyicyclopentadienyl) and M(II) (M = Ru, Os) phosphine complexes containing a cis arrangement of chlorides gives compounds with MS2N2 metallacycles.",

keywords = "tin, sulfur, nitrogen, metathesis, metallacycles, CRYSTAL-STRUCTURE",

author = "SM Aucott and Slawin, \{Alexandra Martha Zoya\} and Woollins, \{John Derek\}",

note = "Phosphorus, Sulf.Silicon",

year = "2001",

language = "English",

volume = "168",

type = "Other",

}

TY - GEN

T1 - Preparation, characterisation and use of [(n-Bu2Sn)S2N2]2 as a metathetical reagent

AU - Aucott, SM

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

N1 - Phosphorus, Sulf.Silicon

PY - 2001

Y1 - 2001

N2 - The dimeric compound [(eta-Bu2Sn)S2N2](2) is readily prepared by addition of eta-Bu2SnCl2 to a liquid ammonia/[S4N3][Cl] reaction mixture. Reaction of [eta-Bu2SnS2N2](2) with mono and dimeric organometallic M(III) (M=Rh, Ir) complexes bearing Cp* ligands (Cp* = 1,2,3,4,5-pentamethyicyclopentadienyl) and M(II) (M = Ru, Os) phosphine complexes containing a cis arrangement of chlorides gives compounds with MS2N2 metallacycles.

AB - The dimeric compound [(eta-Bu2Sn)S2N2](2) is readily prepared by addition of eta-Bu2SnCl2 to a liquid ammonia/[S4N3][Cl] reaction mixture. Reaction of [eta-Bu2SnS2N2](2) with mono and dimeric organometallic M(III) (M=Rh, Ir) complexes bearing Cp* ligands (Cp* = 1,2,3,4,5-pentamethyicyclopentadienyl) and M(II) (M = Ru, Os) phosphine complexes containing a cis arrangement of chlorides gives compounds with MS2N2 metallacycles.

KW - tin

KW - sulfur

KW - nitrogen

KW - metathesis

KW - metallacycles

KW - CRYSTAL-STRUCTURE

UR - https://www.scopus.com/pages/publications/0035648388

M3 - Other contribution

VL - 168

ER -

Preparation, characterisation and use of [(ⁿ-Bu₂Sn)S₂N₂]₂ as a metathetical reagent

Abstract

Keywords

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