Abstract
The dimeric compound [(eta-Bu2Sn)S2N2](2) is readily prepared by addition of eta-Bu2SnCl2 to a liquid ammonia/[S4N3][Cl] reaction mixture. Reaction of [eta-Bu2SnS2N2](2) with mono and dimeric organometallic M(III) (M=Rh, Ir) complexes bearing Cp* ligands (Cp* = 1,2,3,4,5-pentamethyicyclopentadienyl) and M(II) (M = Ru, Os) phosphine complexes containing a cis arrangement of chlorides gives compounds with MS2N2 metallacycles.
Original language | English |
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Volume | 168 |
Publication status | Published - 2001 |
Keywords
- tin
- sulfur
- nitrogen
- metathesis
- metallacycles
- CRYSTAL-STRUCTURE