Preparation and structural studies of [Mo(N3S2){R2(O)PNP(S)R2}2]

TQ Ly; FE Mabbs; Alexandra Martha Zoya Slawin; John Derek Woollins

Preparation and structural studies of [Mo(N₃S₂){R₂(O)PNP(S)R₂}₂]

TQ Ly, FE Mabbs, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of K[N{P(S)R-2}(2)] (R=Ph or Pr-i) with [Mo(N3S2)Cl-3] in CH2Cl2 gave [Mo(N3S2){(Ph-2(O)PNP(S)Ph-2}(2)] (1) and [Mo(N3S2) {Pr-i(2)(O)PNP(S)Pr-i(2)}2] (2), the first examples of molybdenum complexes containing an imidophosphinate Ligand. 1 and 2 have been characterised spectroscopically (IR/Raman, EPR) and by X-ray crystallography: 1 adopts the common puckered conformation for the ME2P2N ring but 2 is the first example of a 'planar' Me2P2N (E=O, S or Se) ring. (C) 1998 Elsevier Science S.A. All rights reserved.

Original language	English
Pages (from-to)	143-146
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	1
Publication status	Published - Apr 1998

Keywords

molybdenum complexes
imidophosphinate complexes
sulfur-nitrogen complexes
crystal structures
SULFUR NITROGEN LIGANDS
CRYSTAL-STRUCTURE
CYCLOTHIAZENO-COMPLEXES
MOLYBDENUM
ADDITIVES

Cite this

@article{cacc9f54bc4f427698e7eafb148b2d48,

title = "Preparation and structural studies of [Mo(N3S2){R2(O)PNP(S)R2}2]",

abstract = "The reaction of K[N{P(S)R-2}(2)] (R=Ph or Pr-i) with [Mo(N3S2)Cl-3] in CH2Cl2 gave [Mo(N3S2){(Ph-2(O)PNP(S)Ph-2}(2)] (1) and [Mo(N3S2) {Pr-i(2)(O)PNP(S)Pr-i(2)}2] (2), the first examples of molybdenum complexes containing an imidophosphinate Ligand. 1 and 2 have been characterised spectroscopically (IR/Raman, EPR) and by X-ray crystallography: 1 adopts the common puckered conformation for the ME2P2N ring but 2 is the first example of a 'planar' Me2P2N (E=O, S or Se) ring. (C) 1998 Elsevier Science S.A. All rights reserved.",

keywords = "molybdenum complexes, imidophosphinate complexes, sulfur-nitrogen complexes, crystal structures, SULFUR NITROGEN LIGANDS, CRYSTAL-STRUCTURE, CYCLOTHIAZENO-COMPLEXES, MOLYBDENUM, ADDITIVES",

author = "TQ Ly and FE Mabbs and Slawin, {Alexandra Martha Zoya} and Woollins, {John Derek}",

year = "1998",

month = apr,

language = "English",

volume = "1",

pages = "143--146",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier Science BV",

}

TY - JOUR

T1 - Preparation and structural studies of [Mo(N3S2){R2(O)PNP(S)R2}2]

AU - Ly, TQ

AU - Mabbs, FE

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

PY - 1998/4

Y1 - 1998/4

N2 - The reaction of K[N{P(S)R-2}(2)] (R=Ph or Pr-i) with [Mo(N3S2)Cl-3] in CH2Cl2 gave [Mo(N3S2){(Ph-2(O)PNP(S)Ph-2}(2)] (1) and [Mo(N3S2) {Pr-i(2)(O)PNP(S)Pr-i(2)}2] (2), the first examples of molybdenum complexes containing an imidophosphinate Ligand. 1 and 2 have been characterised spectroscopically (IR/Raman, EPR) and by X-ray crystallography: 1 adopts the common puckered conformation for the ME2P2N ring but 2 is the first example of a 'planar' Me2P2N (E=O, S or Se) ring. (C) 1998 Elsevier Science S.A. All rights reserved.

AB - The reaction of K[N{P(S)R-2}(2)] (R=Ph or Pr-i) with [Mo(N3S2)Cl-3] in CH2Cl2 gave [Mo(N3S2){(Ph-2(O)PNP(S)Ph-2}(2)] (1) and [Mo(N3S2) {Pr-i(2)(O)PNP(S)Pr-i(2)}2] (2), the first examples of molybdenum complexes containing an imidophosphinate Ligand. 1 and 2 have been characterised spectroscopically (IR/Raman, EPR) and by X-ray crystallography: 1 adopts the common puckered conformation for the ME2P2N ring but 2 is the first example of a 'planar' Me2P2N (E=O, S or Se) ring. (C) 1998 Elsevier Science S.A. All rights reserved.

KW - molybdenum complexes

KW - imidophosphinate complexes

KW - sulfur-nitrogen complexes

KW - crystal structures

KW - SULFUR NITROGEN LIGANDS

KW - CRYSTAL-STRUCTURE

KW - CYCLOTHIAZENO-COMPLEXES

KW - MOLYBDENUM

KW - ADDITIVES

UR - http://www.scopus.com/inward/record.url?scp=0006050559&partnerID=8YFLogxK

M3 - Article

SN - 1387-7003

VL - 1

SP - 143

EP - 146

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Preparation and structural studies of [Mo(N₃S₂){R₂(O)PNP(S)R₂}₂]

Abstract

Keywords

Other files and links

Fingerprint

Cite this