Preparation and structural studies of [Mo(N3S2){R-2(O)PNP(S)R-2}(2)]

T Q  Ly; F  Mabbs; E  Mcinnes; A M Z  Slawin; J D  Woollins

doi:10.1080/10426509708545668

Preparation and structural studies of [Mo(N3S2){R-2(O)PNP(S)R-2}(2)]

T Q Ly, F Mabbs, E Mcinnes, A M Z Slawin, J D Woollins

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Abstract

The compounds [Mo(N3S2){Ph-2(O)PNP(S)Ph-2}(2)] 1 [Mo(N3S2){Pr-1(2)(O)PNP(S)Pr-1(2)}(2)] 2 have been synthesised by treating [MoCl3(N3S2)] With KN(PPh2S)(2) or KN((PPh2S)-Ph-1)(2). X-Ray structures of 1 and 2 have been solved. On complexation, the MoN3S2 ring remained planar, but the Mo(OPNPS)(2) rings are puckered.

Original language	English
Pages (from-to)	497-500
Number of pages	4
Journal	Phosphorus, Sulfur, and Silicon and the Related Elements
Volume	124
Issue number	1
DOIs	https://doi.org/10.1080/10426509708545668
Publication status	Published - 1997

Keywords

molybdenum complex
imidodiphosphinate derivatives
metalla-cycles
sulfur-nitrogen
EPR
COMPLEXES
MOLYBDENUM

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title = "Preparation and structural studies of [Mo(N3S2)\{R-2(O)PNP(S)R-2\}(2)]",

abstract = "The compounds [Mo(N3S2)\{Ph-2(O)PNP(S)Ph-2\}(2)] 1 [Mo(N3S2)\{Pr-1(2)(O)PNP(S)Pr-1(2)\}(2)] 2 have been synthesised by treating [MoCl3(N3S2)] With KN(PPh2S)(2) or KN((PPh2S)-Ph-1)(2). X-Ray structures of 1 and 2 have been solved. On complexation, the MoN3S2 ring remained planar, but the Mo(OPNPS)(2) rings are puckered.",

keywords = "molybdenum complex, imidodiphosphinate derivatives, metalla-cycles, sulfur-nitrogen, EPR, COMPLEXES, MOLYBDENUM",

author = "Ly, \{T Q\} and F Mabbs and E Mcinnes and Slawin, \{A M Z\} and Woollins, \{J D\}",

year = "1997",

doi = "10.1080/10426509708545668",

language = "English",

volume = "124",

pages = "497--500",

journal = "Phosphorus, Sulfur, and Silicon and the Related Elements",

issn = "1042-6507",

publisher = "Taylor and Francis",

number = "1",

}

TY - JOUR

T1 - Preparation and structural studies of [Mo(N3S2){R-2(O)PNP(S)R-2}(2)]

AU - Ly, T Q

AU - Mabbs, F

AU - Mcinnes, E

AU - Slawin, A M Z

AU - Woollins, J D

PY - 1997

Y1 - 1997

N2 - The compounds [Mo(N3S2){Ph-2(O)PNP(S)Ph-2}(2)] 1 [Mo(N3S2){Pr-1(2)(O)PNP(S)Pr-1(2)}(2)] 2 have been synthesised by treating [MoCl3(N3S2)] With KN(PPh2S)(2) or KN((PPh2S)-Ph-1)(2). X-Ray structures of 1 and 2 have been solved. On complexation, the MoN3S2 ring remained planar, but the Mo(OPNPS)(2) rings are puckered.

AB - The compounds [Mo(N3S2){Ph-2(O)PNP(S)Ph-2}(2)] 1 [Mo(N3S2){Pr-1(2)(O)PNP(S)Pr-1(2)}(2)] 2 have been synthesised by treating [MoCl3(N3S2)] With KN(PPh2S)(2) or KN((PPh2S)-Ph-1)(2). X-Ray structures of 1 and 2 have been solved. On complexation, the MoN3S2 ring remained planar, but the Mo(OPNPS)(2) rings are puckered.

KW - molybdenum complex

KW - imidodiphosphinate derivatives

KW - metalla-cycles

KW - sulfur-nitrogen

KW - EPR

KW - COMPLEXES

KW - MOLYBDENUM

UR - https://www.scopus.com/pages/publications/0347704169

U2 - 10.1080/10426509708545668

DO - 10.1080/10426509708545668

M3 - Article

SN - 1042-6507

VL - 124

SP - 497

EP - 500

JO - Phosphorus, Sulfur, and Silicon and the Related Elements

JF - Phosphorus, Sulfur, and Silicon and the Related Elements

IS - 1

ER -

Preparation and structural studies of [Mo(N3S2){R-2(O)PNP(S)R-2}(2)]

Abstract

Keywords

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