Preparation and crystal structures of two forms of trans-[CuCl2{N(H)SPh2}2]; an unusual example of square planar/pseudo-tetrahedral isomerism in a neutral copper(II) complex

PF Kelly; Alexandra Martha Zoya Slawin; KW Waring

doi:10.1039/a704276k

Preparation and crystal structures of two forms of trans-[CuCl₂{N(H)SPh₂}₂]; an unusual example of square planar/pseudo-tetrahedral isomerism in a neutral copper(II) complex

PF Kelly, Alexandra Martha Zoya Slawin, KW Waring

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

At ambient temperatures, in acetonitrile, S,S-diphenylsulfimide reacted with CuCl2 (molar ratio 2:1) to give trans-[CuCl2{N(H)SPh2}(2)]; depending upon the crystallisation technique this can be isolated as either blue (perfect square-planar geometry) or green (pseudo-tetrahedral) crystals which do not interconvert in the solid state.

Original language	English
Pages (from-to)	2853-2854
Number of pages	2
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	17
DOIs	https://doi.org/10.1039/a704276k
Publication status	Published - 7 Sept 1997

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CHEMISTRY

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10.1039/a704276k

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title = "Preparation and crystal structures of two forms of trans-[CuCl2{N(H)SPh2}2]; an unusual example of square planar/pseudo-tetrahedral isomerism in a neutral copper(II) complex",

abstract = "At ambient temperatures, in acetonitrile, S,S-diphenylsulfimide reacted with CuCl2 (molar ratio 2:1) to give trans-[CuCl2{N(H)SPh2}(2)]; depending upon the crystallisation technique this can be isolated as either blue (perfect square-planar geometry) or green (pseudo-tetrahedral) crystals which do not interconvert in the solid state.",

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Preparation and crystal structures of two forms of trans-[CuCl₂{N(H)SPh₂}₂]; an unusual example of square planar/pseudo-tetrahedral isomerism in a neutral copper(II) complex. / Kelly, PF; Slawin, Alexandra Martha Zoya; Waring, KW.
In: Journal of the Chemical Society, Dalton Transactions, No. 17, 07.09.1997, p. 2853-2854.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Preparation and crystal structures of two forms of trans-[CuCl2{N(H)SPh2}2]; an unusual example of square planar/pseudo-tetrahedral isomerism in a neutral copper(II) complex

AU - Kelly, PF

AU - Slawin, Alexandra Martha Zoya

AU - Waring, KW

PY - 1997/9/7

Y1 - 1997/9/7

N2 - At ambient temperatures, in acetonitrile, S,S-diphenylsulfimide reacted with CuCl2 (molar ratio 2:1) to give trans-[CuCl2{N(H)SPh2}(2)]; depending upon the crystallisation technique this can be isolated as either blue (perfect square-planar geometry) or green (pseudo-tetrahedral) crystals which do not interconvert in the solid state.

AB - At ambient temperatures, in acetonitrile, S,S-diphenylsulfimide reacted with CuCl2 (molar ratio 2:1) to give trans-[CuCl2{N(H)SPh2}(2)]; depending upon the crystallisation technique this can be isolated as either blue (perfect square-planar geometry) or green (pseudo-tetrahedral) crystals which do not interconvert in the solid state.

KW - CHEMISTRY

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DO - 10.1039/a704276k

M3 - Article

SN - 0300-9246

SP - 2853

EP - 2854

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 17

ER -

Preparation and crystal structures of two forms of trans-[CuCl₂{N(H)SPh₂}₂]; an unusual example of square planar/pseudo-tetrahedral isomerism in a neutral copper(II) complex

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