Preparation and crystal structure of [(AlBr3)(2)(Se2N2)], the first example of a main-group element adduct of diselenium dinitride

P F  Kelly; A M Z  Slawin

Preparation and crystal structure of [(AlBr3)(2)(Se2N2)], the first example of a main-group element adduct of diselenium dinitride

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Abstract

The room temperature reaction of AlBr3 with Se4N4 in CH2Br2 generated [(AlBr3)(2)(Se2N2)] as an air-sensitive, yellow solid; X-ray crystallography confirmed the presence of the neutral Se2N2 ligand, bridging via two Al-N bonds.

Original language	English
Pages (from-to)	4029-4030
Number of pages	2
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	21
Publication status	Published - 7 Nov 1996

Keywords

ROOM-TEMPERATURE
S2N2
CLEAVAGE
S4N4

Cite this

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title = "Preparation and crystal structure of [(AlBr3)(2)(Se2N2)], the first example of a main-group element adduct of diselenium dinitride",

abstract = "The room temperature reaction of AlBr3 with Se4N4 in CH2Br2 generated [(AlBr3)(2)(Se2N2)] as an air-sensitive, yellow solid; X-ray crystallography confirmed the presence of the neutral Se2N2 ligand, bridging via two Al-N bonds.",

keywords = "ROOM-TEMPERATURE, S2N2, CLEAVAGE, S4N4",

author = "Kelly, \{P F\} and Slawin, \{A M Z\}",

year = "1996",

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journal = "Journal of the Chemical Society, Dalton Transactions",

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T1 - Preparation and crystal structure of [(AlBr3)(2)(Se2N2)], the first example of a main-group element adduct of diselenium dinitride

AU - Kelly, P F

AU - Slawin, A M Z

PY - 1996/11/7

Y1 - 1996/11/7

N2 - The room temperature reaction of AlBr3 with Se4N4 in CH2Br2 generated [(AlBr3)(2)(Se2N2)] as an air-sensitive, yellow solid; X-ray crystallography confirmed the presence of the neutral Se2N2 ligand, bridging via two Al-N bonds.

AB - The room temperature reaction of AlBr3 with Se4N4 in CH2Br2 generated [(AlBr3)(2)(Se2N2)] as an air-sensitive, yellow solid; X-ray crystallography confirmed the presence of the neutral Se2N2 ligand, bridging via two Al-N bonds.

KW - ROOM-TEMPERATURE

KW - S2N2

KW - CLEAVAGE

KW - S4N4

UR - https://www.scopus.com/pages/publications/33748629106

M3 - Article

SN - 0300-9246

SP - 4029

EP - 4030

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 21

ER -

Preparation and crystal structure of [(AlBr3)(2)(Se2N2)], the first example of a main-group element adduct of diselenium dinitride

Abstract

Keywords

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