Preparation and Coordination Chemistry of Ph2PNHNHpy

Alexandra Martha Zoya Slawin; Joanne Wheatley; Matthew V Wheatley; John Derek Woollins

doi:10.1016/S0277-5387(03)00115-3

Preparation and Coordination Chemistry of Ph₂PNHNH_py

Alexandra Martha Zoya Slawin, Joanne Wheatley, Matthew V Wheatley, John Derek Woollins

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

Ph(2)PNHNHpy (1) can be oxidised to form Ph2P(E)NHNHpy (E = O, S, Se, 2-4) or reacted with appropriate metal complexes such as [PtCl2(cod)], [PtMe2(cod)], [Pd(muCl)(eta(3)-C3H5)](2), [RhCl(cod)](2), [RuCl2(eta(3):eta(3)-Cl10H16)](2), [RuCl2(p-Cy)](2), [IrCp*Cl-2](2), and [Cu(MeCN)(4)][PF6] to give a range of new monodentate complexes. All new compounds have been charactersised by elemental analyses, NMR, IR and mass spec. The X-ray structures of Ph(2)PNHNHpy, Ph2P(Se)NHNHpy [RuCl2(eta(3):eta(3)- C10H16)(Ph(2)PNHNHpy-P)] and [IrCp*Cl-2(Ph(2)PNHNHpy-P)] are reported. Apart from monodentate P coordination all of the structures contain hydrazine based NH hydrogen bonding. (C) 2003 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	1397-1405
Number of pages	9
Journal	Polyhedron
Volume	22
Issue number	10
DOIs	https://doi.org/10.1016/S0277-5387(03)00115-3
Publication status	Published - 15 May 2003

Keywords

hydrazine
hydrogen
bonding
structures
RAY STRUCTURAL CHARACTERIZATION
TRIDENTATE LIGAND
DONOR ATOMS
COMPLEXES
PALLADIUM
RHODIUM
CATALYSTS
PNP
HYDROGENATION
HYDRAZIDES

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10.1016/S0277-5387(03)00115-3

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title = "Preparation and Coordination Chemistry of Ph2PNHNHpy",

abstract = "Ph(2)PNHNHpy (1) can be oxidised to form Ph2P(E)NHNHpy (E = O, S, Se, 2-4) or reacted with appropriate metal complexes such as [PtCl2(cod)], [PtMe2(cod)], [Pd(muCl)(eta(3)-C3H5)](2), [RhCl(cod)](2), [RuCl2(eta(3):eta(3)-Cl10H16)](2), [RuCl2(p-Cy)](2), [IrCp*Cl-2](2), and [Cu(MeCN)(4)][PF6] to give a range of new monodentate complexes. All new compounds have been charactersised by elemental analyses, NMR, IR and mass spec. The X-ray structures of Ph(2)PNHNHpy, Ph2P(Se)NHNHpy [RuCl2(eta(3):eta(3)- C10H16)(Ph(2)PNHNHpy-P)] and [IrCp*Cl-2(Ph(2)PNHNHpy-P)] are reported. Apart from monodentate P coordination all of the structures contain hydrazine based NH hydrogen bonding. (C) 2003 Elsevier Science Ltd. All rights reserved.",

keywords = "hydrazine, hydrogen, bonding, structures, RAY STRUCTURAL CHARACTERIZATION, TRIDENTATE LIGAND, DONOR ATOMS, COMPLEXES, PALLADIUM, RHODIUM, CATALYSTS, PNP, HYDROGENATION, HYDRAZIDES",

author = "Slawin, {Alexandra Martha Zoya} and Joanne Wheatley and Wheatley, {Matthew V} and Woollins, {John Derek}",

year = "2003",

month = may,

day = "15",

doi = "10.1016/S0277-5387(03)00115-3",

language = "English",

volume = "22",

pages = "1397--1405",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

number = "10",

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TY - JOUR

T1 - Preparation and Coordination Chemistry of Ph2PNHNHpy

AU - Slawin, Alexandra Martha Zoya

AU - Wheatley, Joanne

AU - Wheatley, Matthew V

AU - Woollins, John Derek

PY - 2003/5/15

Y1 - 2003/5/15

N2 - Ph(2)PNHNHpy (1) can be oxidised to form Ph2P(E)NHNHpy (E = O, S, Se, 2-4) or reacted with appropriate metal complexes such as [PtCl2(cod)], [PtMe2(cod)], [Pd(muCl)(eta(3)-C3H5)](2), [RhCl(cod)](2), [RuCl2(eta(3):eta(3)-Cl10H16)](2), [RuCl2(p-Cy)](2), [IrCp*Cl-2](2), and [Cu(MeCN)(4)][PF6] to give a range of new monodentate complexes. All new compounds have been charactersised by elemental analyses, NMR, IR and mass spec. The X-ray structures of Ph(2)PNHNHpy, Ph2P(Se)NHNHpy [RuCl2(eta(3):eta(3)- C10H16)(Ph(2)PNHNHpy-P)] and [IrCp*Cl-2(Ph(2)PNHNHpy-P)] are reported. Apart from monodentate P coordination all of the structures contain hydrazine based NH hydrogen bonding. (C) 2003 Elsevier Science Ltd. All rights reserved.

AB - Ph(2)PNHNHpy (1) can be oxidised to form Ph2P(E)NHNHpy (E = O, S, Se, 2-4) or reacted with appropriate metal complexes such as [PtCl2(cod)], [PtMe2(cod)], [Pd(muCl)(eta(3)-C3H5)](2), [RhCl(cod)](2), [RuCl2(eta(3):eta(3)-Cl10H16)](2), [RuCl2(p-Cy)](2), [IrCp*Cl-2](2), and [Cu(MeCN)(4)][PF6] to give a range of new monodentate complexes. All new compounds have been charactersised by elemental analyses, NMR, IR and mass spec. The X-ray structures of Ph(2)PNHNHpy, Ph2P(Se)NHNHpy [RuCl2(eta(3):eta(3)- C10H16)(Ph(2)PNHNHpy-P)] and [IrCp*Cl-2(Ph(2)PNHNHpy-P)] are reported. Apart from monodentate P coordination all of the structures contain hydrazine based NH hydrogen bonding. (C) 2003 Elsevier Science Ltd. All rights reserved.

KW - hydrazine

KW - hydrogen

KW - bonding

KW - structures

KW - RAY STRUCTURAL CHARACTERIZATION

KW - TRIDENTATE LIGAND

KW - DONOR ATOMS

KW - COMPLEXES

KW - PALLADIUM

KW - RHODIUM

KW - CATALYSTS

KW - PNP

KW - HYDROGENATION

KW - HYDRAZIDES

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U2 - 10.1016/S0277-5387(03)00115-3

DO - 10.1016/S0277-5387(03)00115-3

M3 - Article

SN - 0277-5387

VL - 22

SP - 1397

EP - 1405

JO - Polyhedron

JF - Polyhedron

IS - 10

ER -

Preparation and Coordination Chemistry of Ph₂PNHNH_py

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