Preparation and Coordination Chemistry of p- (xylylenediamonodiphenyl)phosphine

Alexandra Martha Zoya Slawin; J Wheatley; John Derek Woollins

doi:10.1016/j.poly.2004.09.012

Preparation and Coordination Chemistry of p- (xylylenediamonodiphenyl)phosphine

Alexandra Martha Zoya Slawin
, J Wheatley
, John Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of p-xylene diamine with two equivalents of Ph2PCl in the presence of NEt3, proceeds in thf to give p-(xylylenediaminodiphenyl) phosphine 1 in good yield. 1 was derivatised as the dichalcogenides Ph2P(O)NHCH2(C6H4)CH2NHP(O)Ph-2, Ph2P(S)NHCH2(C6H4)CH2NHP(S)Ph-2 and Ph2P(Se)NHCH2(C6H4)CH2NHP(Se)Ph-2 and the structures of the latter two compounds determined crystallographically. The binuclear compounds [{(PEt3)PtCl2(Ph2PNHCH2))(2)C6H4] (5), [{(PPhMe2) PtCl2(Ph2PNHCH2))(2)C6H4] (6), [{IrCl2(eta(2)-C5Me5)(Ph2PNHCH2)}(2)C6H4] (7) [{RhCl2(eta(5)-C5Me5)(Ph2PNHCH2)}(2)C6H4] (8), [{RuCl2(eta(6)-p-(MeC6H4Pr)-Pr-i)(Ph2PNHCH2)}(2)C6H4] (9), [{Pd(eta(3)-C3H5)Cl(Ph2PNHCH2)}(2)C6H4] (10), [{RhCl(C8H12) (Ph2PNH-CH2)}(2)C6H4] (11), [{AuCl(Ph2PNHCH2)}(2)C4H6] (12) have been prepared and characterised spectroscopically. (C) 2004 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	2569-2574
Number of pages	6
Journal	Polyhedron
Volume	23
DOIs	https://doi.org/10.1016/j.poly.2004.09.012
Publication status	Published - 20 Oct 2004

Keywords

ligand
bidentate
bridging
X-ray
phosphine
COMPLEXES
2,6-BIS(DIPHENYLPHOSPHINO)PYRIDINE
PALLADIUM(II)

Access to Document

10.1016/j.poly.2004.09.012

Handle.net

Persistent link

Cite this

@article{6587395914294957bdbf03791b4af8fa,

title = "Preparation and Coordination Chemistry of p- (xylylenediamonodiphenyl)phosphine",

abstract = "Reaction of p-xylene diamine with two equivalents of Ph2PCl in the presence of NEt3, proceeds in thf to give p-(xylylenediaminodiphenyl) phosphine 1 in good yield. 1 was derivatised as the dichalcogenides Ph2P(O)NHCH2(C6H4)CH2NHP(O)Ph-2, Ph2P(S)NHCH2(C6H4)CH2NHP(S)Ph-2 and Ph2P(Se)NHCH2(C6H4)CH2NHP(Se)Ph-2 and the structures of the latter two compounds determined crystallographically. The binuclear compounds [\{(PEt3)PtCl2(Ph2PNHCH2))(2)C6H4] (5), [\{(PPhMe2) PtCl2(Ph2PNHCH2))(2)C6H4] (6), [\{IrCl2(eta(2)-C5Me5)(Ph2PNHCH2)\}(2)C6H4] (7) [\{RhCl2(eta(5)-C5Me5)(Ph2PNHCH2)\}(2)C6H4] (8), [\{RuCl2(eta(6)-p-(MeC6H4Pr)-Pr-i)(Ph2PNHCH2)\}(2)C6H4] (9), [\{Pd(eta(3)-C3H5)Cl(Ph2PNHCH2)\}(2)C6H4] (10), [\{RhCl(C8H12) (Ph2PNH-CH2)\}(2)C6H4] (11), [\{AuCl(Ph2PNHCH2)\}(2)C4H6] (12) have been prepared and characterised spectroscopically. (C) 2004 Elsevier Ltd. All rights reserved.",

keywords = "ligand, bidentate, bridging, X-ray, phosphine, COMPLEXES, 2,6-BIS(DIPHENYLPHOSPHINO)PYRIDINE, PALLADIUM(II)",

author = "Slawin, \{Alexandra Martha Zoya\} and J Wheatley and Woollins, \{John Derek\}",

year = "2004",

month = oct,

day = "20",

doi = "10.1016/j.poly.2004.09.012",

language = "English",

volume = "23",

pages = "2569--2574",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

}

TY - JOUR

T1 - Preparation and Coordination Chemistry of p- (xylylenediamonodiphenyl)phosphine

AU - Slawin, Alexandra Martha Zoya

AU - Wheatley, J

AU - Woollins, John Derek

PY - 2004/10/20

Y1 - 2004/10/20

N2 - Reaction of p-xylene diamine with two equivalents of Ph2PCl in the presence of NEt3, proceeds in thf to give p-(xylylenediaminodiphenyl) phosphine 1 in good yield. 1 was derivatised as the dichalcogenides Ph2P(O)NHCH2(C6H4)CH2NHP(O)Ph-2, Ph2P(S)NHCH2(C6H4)CH2NHP(S)Ph-2 and Ph2P(Se)NHCH2(C6H4)CH2NHP(Se)Ph-2 and the structures of the latter two compounds determined crystallographically. The binuclear compounds [{(PEt3)PtCl2(Ph2PNHCH2))(2)C6H4] (5), [{(PPhMe2) PtCl2(Ph2PNHCH2))(2)C6H4] (6), [{IrCl2(eta(2)-C5Me5)(Ph2PNHCH2)}(2)C6H4] (7) [{RhCl2(eta(5)-C5Me5)(Ph2PNHCH2)}(2)C6H4] (8), [{RuCl2(eta(6)-p-(MeC6H4Pr)-Pr-i)(Ph2PNHCH2)}(2)C6H4] (9), [{Pd(eta(3)-C3H5)Cl(Ph2PNHCH2)}(2)C6H4] (10), [{RhCl(C8H12) (Ph2PNH-CH2)}(2)C6H4] (11), [{AuCl(Ph2PNHCH2)}(2)C4H6] (12) have been prepared and characterised spectroscopically. (C) 2004 Elsevier Ltd. All rights reserved.

AB - Reaction of p-xylene diamine with two equivalents of Ph2PCl in the presence of NEt3, proceeds in thf to give p-(xylylenediaminodiphenyl) phosphine 1 in good yield. 1 was derivatised as the dichalcogenides Ph2P(O)NHCH2(C6H4)CH2NHP(O)Ph-2, Ph2P(S)NHCH2(C6H4)CH2NHP(S)Ph-2 and Ph2P(Se)NHCH2(C6H4)CH2NHP(Se)Ph-2 and the structures of the latter two compounds determined crystallographically. The binuclear compounds [{(PEt3)PtCl2(Ph2PNHCH2))(2)C6H4] (5), [{(PPhMe2) PtCl2(Ph2PNHCH2))(2)C6H4] (6), [{IrCl2(eta(2)-C5Me5)(Ph2PNHCH2)}(2)C6H4] (7) [{RhCl2(eta(5)-C5Me5)(Ph2PNHCH2)}(2)C6H4] (8), [{RuCl2(eta(6)-p-(MeC6H4Pr)-Pr-i)(Ph2PNHCH2)}(2)C6H4] (9), [{Pd(eta(3)-C3H5)Cl(Ph2PNHCH2)}(2)C6H4] (10), [{RhCl(C8H12) (Ph2PNH-CH2)}(2)C6H4] (11), [{AuCl(Ph2PNHCH2)}(2)C4H6] (12) have been prepared and characterised spectroscopically. (C) 2004 Elsevier Ltd. All rights reserved.

KW - ligand

KW - bidentate

KW - bridging

KW - X-ray

KW - phosphine

KW - COMPLEXES

KW - 2,6-BIS(DIPHENYLPHOSPHINO)PYRIDINE

KW - PALLADIUM(II)

UR - https://www.scopus.com/pages/publications/8844276810

U2 - 10.1016/j.poly.2004.09.012

DO - 10.1016/j.poly.2004.09.012

M3 - Article

SN - 0277-5387

VL - 23

SP - 2569

EP - 2574

JO - Polyhedron

JF - Polyhedron

ER -

Preparation and Coordination Chemistry of p- (xylylenediamonodiphenyl)phosphine

Abstract

Keywords

Access to Document

Handle.net

Other files and links

Fingerprint

Cite this