Preparation and coordination chemistry of N-diallylaminodiphenylphosphine and N-allylaminobis(diphenyl)phosphine

A M Z  Slawin; H L  Milton; J  Wheatley; J D  Woollins

doi:10.1016/j.poly.2004.09.017

Preparation and coordination chemistry of N-diallylaminodiphenylphosphine and N-allylaminobis(diphenyl)phosphine

A M Z Slawin, H L Milton, J Wheatley, J D Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

N-diallylaminodiphenylphosphine and N-allylaminobis(diphenyl)phosphine have been prepared by reaction of the appropriate amine with Ph2PCl. The coordination chemistry of these phosphines has been studied with a range of metals [Pd, Pt, Rh, Ir, Au, Ru, Mo]. Whilst the majority of the complexes are simple bidentate P,P donors, in the case of N-diallylaminodiphenylphosphine-coordination can involve the C=C group or the nitrogen centre. (C) 2004 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	3125-3132
Number of pages	8
Journal	Polyhedron
Volume	23
DOIs	https://doi.org/10.1016/j.poly.2004.09.017
Publication status	Published - 2 Dec 2004

Keywords

phosphine
hemilabile
X-ray structure
TRANSITION-METAL-COMPLEXES
CARBENE COMPLEXES
ORGANIC SYNTHESES
PHOSPHORUS(III) DERIVATIVES
MOLECULAR-STRUCTURE
PHOSPHINE-LIGANDS
BOND-CLEAVAGE
CHELATE
PH2PNHC6H4PPH2
ACID

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title = "Preparation and coordination chemistry of N-diallylaminodiphenylphosphine and N-allylaminobis(diphenyl)phosphine",

abstract = "N-diallylaminodiphenylphosphine and N-allylaminobis(diphenyl)phosphine have been prepared by reaction of the appropriate amine with Ph2PCl. The coordination chemistry of these phosphines has been studied with a range of metals [Pd, Pt, Rh, Ir, Au, Ru, Mo]. Whilst the majority of the complexes are simple bidentate P,P donors, in the case of N-diallylaminodiphenylphosphine-coordination can involve the C=C group or the nitrogen centre. (C) 2004 Elsevier Ltd. All rights reserved.",

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author = "Slawin, {A M Z} and Milton, {H L} and J Wheatley and Woollins, {J D}",

year = "2004",

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doi = "10.1016/j.poly.2004.09.017",

language = "English",

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AU - Slawin, A M Z

AU - Milton, H L

AU - Wheatley, J

AU - Woollins, J D

PY - 2004/12/2

Y1 - 2004/12/2

N2 - N-diallylaminodiphenylphosphine and N-allylaminobis(diphenyl)phosphine have been prepared by reaction of the appropriate amine with Ph2PCl. The coordination chemistry of these phosphines has been studied with a range of metals [Pd, Pt, Rh, Ir, Au, Ru, Mo]. Whilst the majority of the complexes are simple bidentate P,P donors, in the case of N-diallylaminodiphenylphosphine-coordination can involve the C=C group or the nitrogen centre. (C) 2004 Elsevier Ltd. All rights reserved.

AB - N-diallylaminodiphenylphosphine and N-allylaminobis(diphenyl)phosphine have been prepared by reaction of the appropriate amine with Ph2PCl. The coordination chemistry of these phosphines has been studied with a range of metals [Pd, Pt, Rh, Ir, Au, Ru, Mo]. Whilst the majority of the complexes are simple bidentate P,P donors, in the case of N-diallylaminodiphenylphosphine-coordination can involve the C=C group or the nitrogen centre. (C) 2004 Elsevier Ltd. All rights reserved.

KW - phosphine

KW - hemilabile

KW - X-ray structure

KW - TRANSITION-METAL-COMPLEXES

KW - CARBENE COMPLEXES

KW - ORGANIC SYNTHESES

KW - PHOSPHORUS(III) DERIVATIVES

KW - MOLECULAR-STRUCTURE

KW - PHOSPHINE-LIGANDS

KW - BOND-CLEAVAGE

KW - CHELATE

KW - PH2PNHC6H4PPH2

KW - ACID

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U2 - 10.1016/j.poly.2004.09.017

DO - 10.1016/j.poly.2004.09.017

M3 - Article

SN - 0277-5387

VL - 23

SP - 3125

EP - 3132

JO - Polyhedron

JF - Polyhedron

ER -

Preparation and coordination chemistry of N-diallylaminodiphenylphosphine and N-allylaminobis(diphenyl)phosphine

Abstract

Keywords

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