Preparation and coordination chemistry of N-diallylaminodiphenylphosphine and N-allylaminobis(diphenyl)phosphine

A M Z Slawin, H L Milton, J Wheatley, J D Woollins

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)

Abstract

N-diallylaminodiphenylphosphine and N-allylaminobis(diphenyl)phosphine have been prepared by reaction of the appropriate amine with Ph2PCl. The coordination chemistry of these phosphines has been studied with a range of metals [Pd, Pt, Rh, Ir, Au, Ru, Mo]. Whilst the majority of the complexes are simple bidentate P,P donors, in the case of N-diallylaminodiphenylphosphine-coordination can involve the C=C group or the nitrogen centre. (C) 2004 Elsevier Ltd. All rights reserved.

Original languageEnglish
Pages (from-to)3125-3132
Number of pages8
JournalPolyhedron
Volume23
DOIs
Publication statusPublished - 2 Dec 2004

Keywords

  • phosphine
  • hemilabile
  • X-ray structure
  • TRANSITION-METAL-COMPLEXES
  • CARBENE COMPLEXES
  • ORGANIC SYNTHESES
  • PHOSPHORUS(III) DERIVATIVES
  • MOLECULAR-STRUCTURE
  • PHOSPHINE-LIGANDS
  • BOND-CLEAVAGE
  • CHELATE
  • PH2PNHC6H4PPH2
  • ACID

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