Preparation and Coordination Chemistry of allylaminophosphine

Alexandra Martha Zoya Slawin; J Wheatley; John Derek Woollins

doi:10.1002/ejic.200400447

Preparation and Coordination Chemistry of allylaminophosphine

Alexandra Martha Zoya Slawin, J Wheatley, John Derek Woollins

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

Reaction of allylamine with 1 equiv. of Ph2PCl in the presence of NEt3, proceeds in THF to give (allylamino)phosphane 1. 1 has been coordinated as a monodentate P ligand with Au, Pd, Pt, Ru, Rh, Ir and as a bidentate P,allyl ligand to Pt. Reaction of KOtBu with [PtCl2{Ph2PNH(C3H5)}(2)] in methanol gives [Pt{Ph2PNH(C3H8O})(2)]. The X-ray structures of 1.Se and four demonstrative monodentate complexes all reveal intramolecular N-(HCl)-Cl-... hydrogen bonding. The structure of [Pt{Ph2PNH(C3H8O)}(2)] consists of an N-(HO)-O-... hydrogen-bonded dimer in the solid state. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005.

Original language	English
Pages (from-to)	713-720
Number of pages	8
Journal	European Journal of Inorganic Chemistry
DOIs	https://doi.org/10.1002/ejic.200400447
Publication status	Published - 18 Feb 2005

Keywords

phosphanes
alkenes
hemilabile complexes
X-ray structures
OLEFIN COMPLEXES
METAL-COMPLEXES
PHOSPHINE
LIGANDS
HYDROFORMYLATION
CATALYSIS
BACKBONE
CLEAVAGE

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title = "Preparation and Coordination Chemistry of allylaminophosphine",

abstract = "Reaction of allylamine with 1 equiv. of Ph2PCl in the presence of NEt3, proceeds in THF to give (allylamino)phosphane 1. 1 has been coordinated as a monodentate P ligand with Au, Pd, Pt, Ru, Rh, Ir and as a bidentate P,allyl ligand to Pt. Reaction of KOtBu with [PtCl2{Ph2PNH(C3H5)}(2)] in methanol gives [Pt{Ph2PNH(C3H8O})(2)]. The X-ray structures of 1.Se and four demonstrative monodentate complexes all reveal intramolecular N-(HCl)-Cl-... hydrogen bonding. The structure of [Pt{Ph2PNH(C3H8O)}(2)] consists of an N-(HO)-O-... hydrogen-bonded dimer in the solid state. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005.",

keywords = "phosphanes, alkenes, hemilabile complexes, X-ray structures, OLEFIN COMPLEXES, METAL-COMPLEXES, PHOSPHINE, LIGANDS, HYDROFORMYLATION, CATALYSIS, BACKBONE, CLEAVAGE",

author = "Slawin, {Alexandra Martha Zoya} and J Wheatley and Woollins, {John Derek}",

year = "2005",

month = feb,

day = "18",

doi = "10.1002/ejic.200400447",

language = "English",

pages = "713--720",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-Blackwell",

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TY - JOUR

T1 - Preparation and Coordination Chemistry of allylaminophosphine

AU - Slawin, Alexandra Martha Zoya

AU - Wheatley, J

AU - Woollins, John Derek

PY - 2005/2/18

Y1 - 2005/2/18

N2 - Reaction of allylamine with 1 equiv. of Ph2PCl in the presence of NEt3, proceeds in THF to give (allylamino)phosphane 1. 1 has been coordinated as a monodentate P ligand with Au, Pd, Pt, Ru, Rh, Ir and as a bidentate P,allyl ligand to Pt. Reaction of KOtBu with [PtCl2{Ph2PNH(C3H5)}(2)] in methanol gives [Pt{Ph2PNH(C3H8O})(2)]. The X-ray structures of 1.Se and four demonstrative monodentate complexes all reveal intramolecular N-(HCl)-Cl-... hydrogen bonding. The structure of [Pt{Ph2PNH(C3H8O)}(2)] consists of an N-(HO)-O-... hydrogen-bonded dimer in the solid state. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005.

AB - Reaction of allylamine with 1 equiv. of Ph2PCl in the presence of NEt3, proceeds in THF to give (allylamino)phosphane 1. 1 has been coordinated as a monodentate P ligand with Au, Pd, Pt, Ru, Rh, Ir and as a bidentate P,allyl ligand to Pt. Reaction of KOtBu with [PtCl2{Ph2PNH(C3H5)}(2)] in methanol gives [Pt{Ph2PNH(C3H8O})(2)]. The X-ray structures of 1.Se and four demonstrative monodentate complexes all reveal intramolecular N-(HCl)-Cl-... hydrogen bonding. The structure of [Pt{Ph2PNH(C3H8O)}(2)] consists of an N-(HO)-O-... hydrogen-bonded dimer in the solid state. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005.

KW - phosphanes

KW - alkenes

KW - hemilabile complexes

KW - X-ray structures

KW - OLEFIN COMPLEXES

KW - METAL-COMPLEXES

KW - PHOSPHINE

KW - LIGANDS

KW - HYDROFORMYLATION

KW - CATALYSIS

KW - BACKBONE

KW - CLEAVAGE

UR - http://www.scopus.com/inward/record.url?scp=14844288266&partnerID=8YFLogxK

U2 - 10.1002/ejic.200400447

DO - 10.1002/ejic.200400447

M3 - Article

SN - 1434-1948

SP - 713

EP - 720

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

ER -

Preparation and Coordination Chemistry of allylaminophosphine

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Keywords

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