Preparation and Characterization of a New Layered Magnesium Phosphate: MgHPO4 · 1.2H2O

J. Chen; S. Natarajan; P. A. Wright; R. H. Jones; J. M. Thomas; C. R.A. Catlow; R. P. Townsend

doi:10.1006/jssc.1993.1130

Preparation and Characterization of a New Layered Magnesium Phosphate: MgHPO₄ · 1.2H₂O

J. Chen^*
, S. Natarajan
, P. A. Wright
, R. H. Jones
, J. M. Thomas
, C. R.A. Catlow
, R. P. Townsend

^*Corresponding author for this work

Research output: Contribution to journal › Editorial › peer-review

Abstract

A new hydrated phosphate of magnesium with a layered structure was prepared hydrothermally under mild conditions. Provided it is not heated beyond 200°C, this solid undergoes reversible dehydration-rehydration with the layered structure remaining intact. The as-prepared precursor is orthorhombic (a = 9.274, b = 8.053, and c = 10.920 Å), the likely space group being P2₁2₁2. At ca. 500°C, the compound transforms to Mg₂P₂O₇.

Original language	English
Pages (from-to)	519-522
Number of pages	4
Journal	Journal of Solid State Chemistry
Volume	103
Issue number	2
DOIs	https://doi.org/10.1006/jssc.1993.1130
Publication status	Published - 1 Apr 1993

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@article{68e4b52b61f44b62bc5184d7a2ac1174,

title = "Preparation and Characterization of a New Layered Magnesium Phosphate: MgHPO4 · 1.2H2O",

abstract = "A new hydrated phosphate of magnesium with a layered structure was prepared hydrothermally under mild conditions. Provided it is not heated beyond 200°C, this solid undergoes reversible dehydration-rehydration with the layered structure remaining intact. The as-prepared precursor is orthorhombic (a = 9.274, b = 8.053, and c = 10.920 {\AA}), the likely space group being P21212. At ca. 500°C, the compound transforms to Mg2P2O7.",

author = "J. Chen and S. Natarajan and Wright, \{P. A.\} and Jones, \{R. H.\} and Thomas, \{J. M.\} and Catlow, \{C. R.A.\} and Townsend, \{R. P.\}",

year = "1993",

month = apr,

day = "1",

doi = "10.1006/jssc.1993.1130",

language = "English",

volume = "103",

pages = "519--522",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press/Elsevier ",

number = "2",

}

TY - JOUR

T1 - Preparation and Characterization of a New Layered Magnesium Phosphate

T2 - MgHPO4 · 1.2H2O

AU - Chen, J.

AU - Natarajan, S.

AU - Wright, P. A.

AU - Jones, R. H.

AU - Thomas, J. M.

AU - Catlow, C. R.A.

AU - Townsend, R. P.

PY - 1993/4/1

Y1 - 1993/4/1

N2 - A new hydrated phosphate of magnesium with a layered structure was prepared hydrothermally under mild conditions. Provided it is not heated beyond 200°C, this solid undergoes reversible dehydration-rehydration with the layered structure remaining intact. The as-prepared precursor is orthorhombic (a = 9.274, b = 8.053, and c = 10.920 Å), the likely space group being P21212. At ca. 500°C, the compound transforms to Mg2P2O7.

AB - A new hydrated phosphate of magnesium with a layered structure was prepared hydrothermally under mild conditions. Provided it is not heated beyond 200°C, this solid undergoes reversible dehydration-rehydration with the layered structure remaining intact. The as-prepared precursor is orthorhombic (a = 9.274, b = 8.053, and c = 10.920 Å), the likely space group being P21212. At ca. 500°C, the compound transforms to Mg2P2O7.

UR - https://www.scopus.com/pages/publications/0008134475

U2 - 10.1006/jssc.1993.1130

DO - 10.1006/jssc.1993.1130

M3 - Editorial

AN - SCOPUS:0008134475

SN - 0022-4596

VL - 103

SP - 519

EP - 522

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 2

ER -

Preparation and Characterization of a New Layered Magnesium Phosphate: MgHPO₄ · 1.2H₂O

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