Post-synthetic modification of zinc metal-organic frameworks through palladium- catalysed carbon-carbon bond formation

Andrew D. Burrows; Laura C. Fisher; Timothy J. Mays; Sean P. Rigby; Sharon E. Ashbrook; Daniel M. Dawson

doi:10.1016/j.jorganchem.2015.03.031

Post-synthetic modification of zinc metal-organic frameworks through palladium- catalysed carbon-carbon bond formation

Andrew D. Burrows^*, Laura C. Fisher, Timothy J. Mays, Sean P. Rigby, Sharon E. Ashbrook, Daniel M. Dawson

^*Corresponding author for this work

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Abstract

Post-synthetic Suzuki coupling reactions have been undertaken on the halide-functionalised metal-organic frameworks (MOFs) [Zn₄O(bdc-Br)₃] (bdc-Br = 2-bromo-1,4-benzenedicarboxylate, IRMOF-2) and [Zn₄O(bdc-I)₃] (bdc-I = 2-iodo-1,4-benzenedicarboxylate). Although the bulky catalyst employed leads to relatively low conversions, the use of core–shell MOFs demonstrates that the reactions are not confined to the crystal surfaces.

Original language	English
Pages (from-to)	134-138
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	792
Early online date	9 Apr 2015
DOIs	https://doi.org/10.1016/j.jorganchem.2015.03.031
Publication status	Published - 1 Sept 2015

Keywords

Metal-organic framework
Post-synthetic modification
Zinc
Palladium
Suzuki coupling

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10.1016/j.jorganchem.2015.03.031

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© 2015 Elsevier B.V. All rights reserved. This is the author’s version of a work that was accepted for publication in Journal of Organometallic Chemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Organometallic Chemistry, [VOL#, ISSUE#, 2015] DOI:10.1016/j.jorganchem.2015.03.031
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Cite this

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title = "Post-synthetic modification of zinc metal-organic frameworks through palladium- catalysed carbon-carbon bond formation",

abstract = "Post-synthetic Suzuki coupling reactions have been undertaken on the halide-functionalised metal-organic frameworks (MOFs) [Zn4O(bdc-Br)3] (bdc-Br = 2-bromo-1,4-benzenedicarboxylate, IRMOF-2) and [Zn4O(bdc-I)3] (bdc-I = 2-iodo-1,4-benzenedicarboxylate). Although the bulky catalyst employed leads to relatively low conversions, the use of core–shell MOFs demonstrates that the reactions are not confined to the crystal surfaces.",

keywords = "Metal-organic framework, Post-synthetic modification, Zinc, Palladium, Suzuki coupling",

author = "Burrows, {Andrew D.} and Fisher, {Laura C.} and Mays, {Timothy J.} and Rigby, {Sean P.} and Ashbrook, {Sharon E.} and Dawson, {Daniel M.}",

note = "The EPSRC is thanked for financial support. ",

year = "2015",

month = sep,

day = "1",

doi = "10.1016/j.jorganchem.2015.03.031",

language = "English",

volume = "792",

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journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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TY - JOUR

T1 - Post-synthetic modification of zinc metal-organic frameworks through palladium- catalysed carbon-carbon bond formation

AU - Burrows, Andrew D.

AU - Fisher, Laura C.

AU - Mays, Timothy J.

AU - Rigby, Sean P.

AU - Ashbrook, Sharon E.

AU - Dawson, Daniel M.

N1 - The EPSRC is thanked for financial support.

PY - 2015/9/1

Y1 - 2015/9/1

N2 - Post-synthetic Suzuki coupling reactions have been undertaken on the halide-functionalised metal-organic frameworks (MOFs) [Zn4O(bdc-Br)3] (bdc-Br = 2-bromo-1,4-benzenedicarboxylate, IRMOF-2) and [Zn4O(bdc-I)3] (bdc-I = 2-iodo-1,4-benzenedicarboxylate). Although the bulky catalyst employed leads to relatively low conversions, the use of core–shell MOFs demonstrates that the reactions are not confined to the crystal surfaces.

AB - Post-synthetic Suzuki coupling reactions have been undertaken on the halide-functionalised metal-organic frameworks (MOFs) [Zn4O(bdc-Br)3] (bdc-Br = 2-bromo-1,4-benzenedicarboxylate, IRMOF-2) and [Zn4O(bdc-I)3] (bdc-I = 2-iodo-1,4-benzenedicarboxylate). Although the bulky catalyst employed leads to relatively low conversions, the use of core–shell MOFs demonstrates that the reactions are not confined to the crystal surfaces.

KW - Metal-organic framework

KW - Post-synthetic modification

KW - Zinc

KW - Palladium

KW - Suzuki coupling

UR - http://www.sciencedirect.com/science/article/pii/S0022328X15001904#appd001

U2 - 10.1016/j.jorganchem.2015.03.031

DO - 10.1016/j.jorganchem.2015.03.031

M3 - Article

SN - 0022-328X

VL - 792

SP - 134

EP - 138

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Post-synthetic modification of zinc metal-organic frameworks through palladium- catalysed carbon-carbon bond formation

Abstract

Keywords

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