Abstract
Porous single crystals of cubic Co3O4, NiO, In2O3 and CeO2 were fabricated using cage-containing SBA-16 and FDU-12 as hard templates, and characterized by X-ray powder diffraction, high-resolution transmission electron microscopy and N-2 adsorption/desorption. Unsuccessful synthesis of non-cubic metal oxides implies that the symmetries of the oxide structures have a significant effect on crystal growth inside the mesopore networks in these templates. A possible mechanism of crystal growth in the confined spherical cages is discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 4947-4952 |
| Number of pages | 6 |
| Journal | Journal of Materials Chemistry |
| Volume | 17 |
| Issue number | 47 |
| DOIs | |
| Publication status | Published - 2007 |
Keywords
- SINGLE-CRYSTALS
- CO
- FRAMEWORKS
- NANOWIRES
- MECHANISM
- COPOLYMER
- TRIBLOCK
- SYSTEM
- GROWTH
- ROUTE
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