Polyporous Metal-Coordination Frameworks

Jeremiah J. Gassensmith, Ronald A. Smaldone, Ross S. Forgan, Christopher E. Wilmer, David B. Cordes, Youssry Y. Botros, Alexandra Martha Zoya Slawin, Randall Q. Snurr, J. Fraser Stoddart

Research output: Contribution to journalArticlepeer-review

31 Citations (Scopus)

Abstract

Starting from a chiral building block-alpha-cyclodextrin-and rubidium salts, the crystallization of a complex of chiral helices, which constitute a "green" porous coordination polymer, has been realized. Cyclodextrin molecules coordinated by rubidium ions form porous, infinitely long left-handed helical channels, interdigitated with each other. A theoretical examination of the potential of this new material to act as a medium for chiral separation is presented.

Original languageEnglish
Pages (from-to)1460-1463
Number of pages4
JournalOrganic Letters
Volume14
Issue number6
DOIs
Publication statusPublished - 16 Mar 2012

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