Polyporous Metal-Coordination Frameworks

Jeremiah J. Gassensmith; Ronald A. Smaldone; Ross S. Forgan; Christopher E. Wilmer; David B. Cordes; Youssry Y. Botros; Alexandra Martha Zoya Slawin; Randall Q. Snurr; J. Fraser Stoddart

doi:10.1021/ol300199a

Polyporous Metal-Coordination Frameworks

Jeremiah J. Gassensmith, Ronald A. Smaldone, Ross S. Forgan, Christopher E. Wilmer, David B. Cordes, Youssry Y. Botros, Alexandra Martha Zoya Slawin, Randall Q. Snurr, J. Fraser Stoddart

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

Starting from a chiral building block-alpha-cyclodextrin-and rubidium salts, the crystallization of a complex of chiral helices, which constitute a "green" porous coordination polymer, has been realized. Cyclodextrin molecules coordinated by rubidium ions form porous, infinitely long left-handed helical channels, interdigitated with each other. A theoretical examination of the potential of this new material to act as a medium for chiral separation is presented.

Original language	English
Pages (from-to)	1460-1463
Number of pages	4
Journal	Organic Letters
Volume	14
Issue number	6
DOIs	https://doi.org/10.1021/ol300199a
Publication status	Published - 16 Mar 2012

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10.1021/ol300199a

Structural Mechanostereochemistry: International Collaboration in Chemistry: Structral Mechanostereochemistry of Mechanically interlocked Polymers and Networks
Slawin, A. M. Z. (PI)
EPSRC
18/01/10 → 17/01/13
Project: Standard

Cite this

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title = "Polyporous Metal-Coordination Frameworks",

abstract = "Starting from a chiral building block-alpha-cyclodextrin-and rubidium salts, the crystallization of a complex of chiral helices, which constitute a {"}green{"} porous coordination polymer, has been realized. Cyclodextrin molecules coordinated by rubidium ions form porous, infinitely long left-handed helical channels, interdigitated with each other. A theoretical examination of the potential of this new material to act as a medium for chiral separation is presented.",

author = "Gassensmith, {Jeremiah J.} and Smaldone, {Ronald A.} and Forgan, {Ross S.} and Wilmer, {Christopher E.} and Cordes, {David B.} and Botros, {Youssry Y.} and Slawin, {Alexandra Martha Zoya} and Snurr, {Randall Q.} and Stoddart, {J. Fraser}",

year = "2012",

month = mar,

day = "16",

doi = "10.1021/ol300199a",

language = "English",

volume = "14",

pages = "1460--1463",

journal = "Organic Letters",

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TY - JOUR

T1 - Polyporous Metal-Coordination Frameworks

AU - Gassensmith, Jeremiah J.

AU - Smaldone, Ronald A.

AU - Forgan, Ross S.

AU - Wilmer, Christopher E.

AU - Cordes, David B.

AU - Botros, Youssry Y.

AU - Slawin, Alexandra Martha Zoya

AU - Snurr, Randall Q.

AU - Stoddart, J. Fraser

PY - 2012/3/16

Y1 - 2012/3/16

N2 - Starting from a chiral building block-alpha-cyclodextrin-and rubidium salts, the crystallization of a complex of chiral helices, which constitute a "green" porous coordination polymer, has been realized. Cyclodextrin molecules coordinated by rubidium ions form porous, infinitely long left-handed helical channels, interdigitated with each other. A theoretical examination of the potential of this new material to act as a medium for chiral separation is presented.

AB - Starting from a chiral building block-alpha-cyclodextrin-and rubidium salts, the crystallization of a complex of chiral helices, which constitute a "green" porous coordination polymer, has been realized. Cyclodextrin molecules coordinated by rubidium ions form porous, infinitely long left-handed helical channels, interdigitated with each other. A theoretical examination of the potential of this new material to act as a medium for chiral separation is presented.

U2 - 10.1021/ol300199a

DO - 10.1021/ol300199a

M3 - Article

SN - 1523-7060

VL - 14

SP - 1460

EP - 1463

JO - Organic Letters

JF - Organic Letters

IS - 6

ER -

Polyporous Metal-Coordination Frameworks

Abstract

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Projects

Structural Mechanostereochemistry: International Collaboration in Chemistry: Structral Mechanostereochemistry of Mechanically interlocked Polymers and Networks

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