Polymeric and bimetallic complexes of diisopropyl monothiophosphate

J R  PHILLIPS; J C  POAT; A M Z  SLAWIN; D J  WILLIAMS; P T  WOOD; J D  WOOLLINS

doi:10.1039/DT9950002369

Polymeric and bimetallic complexes of diisopropyl monothiophosphate

J R PHILLIPS, J C POAT, A M Z SLAWIN, D J WILLIAMS, P T WOOD, J D WOOLLINS

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Abstract

The single stage preparation of M[O(S)P(OPri)(2)](n) (n = 2, M = Zn 1, Co 2 or Cd 3; n = 1, M = NH4+ 4) from HPO(OPri)(2), sulfur and ZnO, CoCO3, CdCO3 or NH3 has been achieved. The reaction of 1 with cis-[PtCl2(PMe(2)Ph)(2)] and [PPh4(])[MCl(3)(PMe(2)Ph)] (M = Pt or Pd) gave [(PMe(2)Ph)(2)Pt{O(S)P(OPri)(2)}2ZnCl2] 5 and [(PMe(2)Ph)M{O(S)P(OPri)(2)}3ZnCl] (M = Pd 6 or Pt 7) respectively. The crystal structures of 3, 6 and 7 have been determined. The cadmium complex 3 exists as Cd-2[O(S)P(OPri)(2)](3) units linked by additional monothiophosphate ligands into polymeric chains. Complexes 6 and 7 are isomorphous and contain tetrahedral zinc centres linked to square-planar platinum atoms with polymer formation being inhibited by the presence of PMe(2)Ph ligands.

Original language	English
Pages (from-to)	2369-2375
Number of pages	7
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	14
DOIs	https://doi.org/10.1039/DT9950002369
Publication status	Published - 21 Jul 1995

Keywords

ZINC(II) BIS(O,O'-DIALKYL DITHIOPHOSPHATES)
NITROGEN BASES
CRYSTAL

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10.1039/DT9950002369

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@article{6abfee3fa90548af81f13949adcdbcea,

title = "Polymeric and bimetallic complexes of diisopropyl monothiophosphate",

abstract = "The single stage preparation of M[O(S)P(OPri)(2)](n) (n = 2, M = Zn 1, Co 2 or Cd 3; n = 1, M = NH4+ 4) from HPO(OPri)(2), sulfur and ZnO, CoCO3, CdCO3 or NH3 has been achieved. The reaction of 1 with cis-[PtCl2(PMe(2)Ph)(2)] and [PPh4(])[MCl(3)(PMe(2)Ph)] (M = Pt or Pd) gave [(PMe(2)Ph)(2)Pt{O(S)P(OPri)(2)}2ZnCl2] 5 and [(PMe(2)Ph)M{O(S)P(OPri)(2)}3ZnCl] (M = Pd 6 or Pt 7) respectively. The crystal structures of 3, 6 and 7 have been determined. The cadmium complex 3 exists as Cd-2[O(S)P(OPri)(2)](3) units linked by additional monothiophosphate ligands into polymeric chains. Complexes 6 and 7 are isomorphous and contain tetrahedral zinc centres linked to square-planar platinum atoms with polymer formation being inhibited by the presence of PMe(2)Ph ligands.",

keywords = "ZINC(II) BIS(O,O'-DIALKYL DITHIOPHOSPHATES), NITROGEN BASES, CRYSTAL",

author = "PHILLIPS, {J R} and POAT, {J C} and SLAWIN, {A M Z} and WILLIAMS, {D J} and WOOD, {P T} and WOOLLINS, {J D}",

year = "1995",

month = jul,

day = "21",

doi = "10.1039/DT9950002369",

language = "English",

pages = "2369--2375",

journal = "Journal of the Chemical Society, Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Polymeric and bimetallic complexes of diisopropyl monothiophosphate

AU - PHILLIPS, J R

AU - POAT, J C

AU - SLAWIN, A M Z

AU - WILLIAMS, D J

AU - WOOD, P T

AU - WOOLLINS, J D

PY - 1995/7/21

Y1 - 1995/7/21

N2 - The single stage preparation of M[O(S)P(OPri)(2)](n) (n = 2, M = Zn 1, Co 2 or Cd 3; n = 1, M = NH4+ 4) from HPO(OPri)(2), sulfur and ZnO, CoCO3, CdCO3 or NH3 has been achieved. The reaction of 1 with cis-[PtCl2(PMe(2)Ph)(2)] and [PPh4(])[MCl(3)(PMe(2)Ph)] (M = Pt or Pd) gave [(PMe(2)Ph)(2)Pt{O(S)P(OPri)(2)}2ZnCl2] 5 and [(PMe(2)Ph)M{O(S)P(OPri)(2)}3ZnCl] (M = Pd 6 or Pt 7) respectively. The crystal structures of 3, 6 and 7 have been determined. The cadmium complex 3 exists as Cd-2[O(S)P(OPri)(2)](3) units linked by additional monothiophosphate ligands into polymeric chains. Complexes 6 and 7 are isomorphous and contain tetrahedral zinc centres linked to square-planar platinum atoms with polymer formation being inhibited by the presence of PMe(2)Ph ligands.

AB - The single stage preparation of M[O(S)P(OPri)(2)](n) (n = 2, M = Zn 1, Co 2 or Cd 3; n = 1, M = NH4+ 4) from HPO(OPri)(2), sulfur and ZnO, CoCO3, CdCO3 or NH3 has been achieved. The reaction of 1 with cis-[PtCl2(PMe(2)Ph)(2)] and [PPh4(])[MCl(3)(PMe(2)Ph)] (M = Pt or Pd) gave [(PMe(2)Ph)(2)Pt{O(S)P(OPri)(2)}2ZnCl2] 5 and [(PMe(2)Ph)M{O(S)P(OPri)(2)}3ZnCl] (M = Pd 6 or Pt 7) respectively. The crystal structures of 3, 6 and 7 have been determined. The cadmium complex 3 exists as Cd-2[O(S)P(OPri)(2)](3) units linked by additional monothiophosphate ligands into polymeric chains. Complexes 6 and 7 are isomorphous and contain tetrahedral zinc centres linked to square-planar platinum atoms with polymer formation being inhibited by the presence of PMe(2)Ph ligands.

KW - ZINC(II) BIS(O,O'-DIALKYL DITHIOPHOSPHATES)

KW - NITROGEN BASES

KW - CRYSTAL

U2 - 10.1039/DT9950002369

DO - 10.1039/DT9950002369

M3 - Article

SN - 0300-9246

SP - 2369

EP - 2375

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 14

ER -

Polymeric and bimetallic complexes of diisopropyl monothiophosphate

Abstract

Keywords

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