Polymer precursors from catalytic reactions of natural oils

Marc R. L. Furst; Ronan Le Goff; Dorothee Quinzler; Stefan Mecking; Catherine H. Botting; David J. Cole-Hamilton

doi:10.1039/c1gc16094j

Polymer precursors from catalytic reactions of natural oils

Marc R. L. Furst, Ronan Le Goff, Dorothee Quinzler, Stefan Mecking, Catherine H. Botting, David J. Cole-Hamilton

Research output: Contribution to journal › Article › peer-review

Abstract

Dimethyl 1,19-nonadecanedioate is produced from the methoxycarbonylation of commercial olive, rapeseed or sunflower oils in the presence of a catalyst derived from [Pd-2(dba)(3)], bis(ditertiarybutylphosphinomethyl) benzene (BDTBPMB) and methanesulphonic acid (MSA). The diester is then hydrogenated to 1,19-nonadecanediol using Ru/1,1,1-tris- (diphenylphosphinemethyl) ethane (triphos). 1,19-Nonadecadienoic acid is hydrogenated to short chain oligoesters, which can themselves be hydrogenated to 1,19-nonadecanol by hydrogenation in the presence of water.

Original language	English
Pages (from-to)	472-477
Number of pages	6
Journal	Green Chemistry
Volume	14
Issue number	2
DOIs	https://doi.org/10.1039/c1gc16094j
Publication status	Published - 2012

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title = "Polymer precursors from catalytic reactions of natural oils",

abstract = "Dimethyl 1,19-nonadecanedioate is produced from the methoxycarbonylation of commercial olive, rapeseed or sunflower oils in the presence of a catalyst derived from [Pd-2(dba)(3)], bis(ditertiarybutylphosphinomethyl) benzene (BDTBPMB) and methanesulphonic acid (MSA). The diester is then hydrogenated to 1,19-nonadecanediol using Ru/1,1,1-tris- (diphenylphosphinemethyl) ethane (triphos). 1,19-Nonadecadienoic acid is hydrogenated to short chain oligoesters, which can themselves be hydrogenated to 1,19-nonadecanol by hydrogenation in the presence of water.",

author = "Furst, {Marc R. L.} and {Le Goff}, Ronan and Dorothee Quinzler and Stefan Mecking and Botting, {Catherine H.} and Cole-Hamilton, {David J.}",

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language = "English",

volume = "14",

pages = "472--477",

journal = "Green Chemistry",

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publisher = "Royal Society of Chemistry",

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T1 - Polymer precursors from catalytic reactions of natural oils

AU - Furst, Marc R. L.

AU - Le Goff, Ronan

AU - Quinzler, Dorothee

AU - Mecking, Stefan

AU - Botting, Catherine H.

AU - Cole-Hamilton, David J.

PY - 2012

Y1 - 2012

N2 - Dimethyl 1,19-nonadecanedioate is produced from the methoxycarbonylation of commercial olive, rapeseed or sunflower oils in the presence of a catalyst derived from [Pd-2(dba)(3)], bis(ditertiarybutylphosphinomethyl) benzene (BDTBPMB) and methanesulphonic acid (MSA). The diester is then hydrogenated to 1,19-nonadecanediol using Ru/1,1,1-tris- (diphenylphosphinemethyl) ethane (triphos). 1,19-Nonadecadienoic acid is hydrogenated to short chain oligoesters, which can themselves be hydrogenated to 1,19-nonadecanol by hydrogenation in the presence of water.

AB - Dimethyl 1,19-nonadecanedioate is produced from the methoxycarbonylation of commercial olive, rapeseed or sunflower oils in the presence of a catalyst derived from [Pd-2(dba)(3)], bis(ditertiarybutylphosphinomethyl) benzene (BDTBPMB) and methanesulphonic acid (MSA). The diester is then hydrogenated to 1,19-nonadecanediol using Ru/1,1,1-tris- (diphenylphosphinemethyl) ethane (triphos). 1,19-Nonadecadienoic acid is hydrogenated to short chain oligoesters, which can themselves be hydrogenated to 1,19-nonadecanol by hydrogenation in the presence of water.

U2 - 10.1039/c1gc16094j

DO - 10.1039/c1gc16094j

M3 - Article

SN - 1463-9262

VL - 14

SP - 472

EP - 477

JO - Green Chemistry

JF - Green Chemistry

IS - 2

ER -

Polymer precursors from catalytic reactions of natural oils

Abstract

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