Poly[[chlorido-(1,10-phenanthroline-κ2N,N′)copper(II)]-μ3-1,1,3,3-tetra-cyano-2-eth-oxy-propenido- κ3N:N′:N′′]: coordination polymer sheets linked into bilayers by hydrogen bonds

Z. Setifi; F. Setifi; L. El Ammari; M. El-Ghozzi; J. Sopková-De Oliveira Santos; H. Merazig; C. Glidewell

doi:10.1107/S2053229613032804

Poly[[chlorido-(1,10-phenanthroline-κ²N,N′)copper(II)]-μ₃-1,1,3,3-tetra-cyano-2-eth-oxy-propenido- κ³N:N′:N′′]: coordination polymer sheets linked into bilayers by hydrogen bonds

Z. Setifi
, F. Setifi
, L. El Ammari
, M. El-Ghozzi
, J. Sopková-De Oliveira Santos
, H. Merazig
, C. Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, [Cu(C₉H₅N₄O)Cl(C₁₂H₈N₂)] n or [Cu(tcnoet)Cl(phen)] n , where phen is 1,10-phenanthroline and tcnoet is 1,1,3,3-tetra-cyano-2-eth- oxy-propenide, the axially elongated (4 + 2) coordination polyhedron around the Cu^II centre contains N atoms from three different tcnoet ligands. The resulting coordination polymer takes the form of sheets which are linked in pairs by a single C - H⋯N hydrogen bond to form bilayers. The bond lengths provide evidence for significant bond fixation in the phen ligand and extensive electronic delocalization in the tcnoet ligand, where the two -C(CN)₂ units are rotated, in conrotatory fashion, out of the plane of the central C₃O fragment.

Original language	English
Pages (from-to)	19-22
Number of pages	4
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	70
Issue number	1
DOIs	https://doi.org/10.1107/S2053229613032804
Publication status	Published - 1 Jan 2014

Keywords

Crystal structure
Coordination polymer
Hydrogen bonding
Anionic polynitrile ligands
Tcnoet ligands
1,1,3,3-tetracyano-2-ethoxypropenide
(4+2) coordination polyhedron
Copper complex

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10.1107/S2053229613032804

Glidewell-2014_SC_Poly
© 2014 International Union of Crystallography.
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Setifi, Z., Setifi, F., El Ammari, L., El-Ghozzi, M., Sopková-De Oliveira Santos, J., Merazig, H., & Glidewell, C. (2014). Poly[[chlorido-(1,10-phenanthroline-κ²N,N′)copper(II)]-μ₃-1,1,3,3-tetra-cyano-2-eth-oxy-propenido- κ³N:N′:N′′]: coordination polymer sheets linked into bilayers by hydrogen bonds. Acta Crystallographica Section C: Crystal Structure Communications, 70(1), 19-22. https://doi.org/10.1107/S2053229613032804

@article{2228b5bc83b340fbbcef78892ede1361,

title = "Poly[[chlorido-(1,10-phenanthroline-κ2N,N′)copper(II)]-μ3-1,1,3,3-tetra-cyano-2-eth-oxy-propenido- κ3N:N′:N′′]: coordination polymer sheets linked into bilayers by hydrogen bonds",

abstract = "In the title compound, [Cu(C9H5N4O)Cl(C12H8N2)] n or [Cu(tcnoet)Cl(phen)] n , where phen is 1,10-phenanthroline and tcnoet is 1,1,3,3-tetra-cyano-2-eth- oxy-propenide, the axially elongated (4 + 2) coordination polyhedron around the CuII centre contains N atoms from three different tcnoet ligands. The resulting coordination polymer takes the form of sheets which are linked in pairs by a single C - H⋯N hydrogen bond to form bilayers. The bond lengths provide evidence for significant bond fixation in the phen ligand and extensive electronic delocalization in the tcnoet ligand, where the two -C(CN)2 units are rotated, in conrotatory fashion, out of the plane of the central C3O fragment.",

keywords = "Crystal structure, Coordination polymer, Hydrogen bonding, Anionic polynitrile ligands, Tcnoet ligands, 1,1,3,3-tetracyano-2-ethoxypropenide, (4+2) coordination polyhedron, Copper complex",

author = "Z. Setifi and F. Setifi and \{El Ammari\}, L. and M. El-Ghozzi and \{Sopkov{\'a}-De Oliveira Santos\}, J. and H. Merazig and C. Glidewell",

note = "The authors acknowledge the Algerian DG–RSDT (Direction Generale de la Recherche Scientifique et du Developpement Technologique) and the Algerian ATRST (Agence Thematique de Recherche en Sciences et Technologie; PNR project) for financial support. ZS thanks Sandra Lebaroud for her help in preparing the manuscript and the Unit of Support for Technical and Scientific Research (UATRS, CNRST) for the X-ray measurements.",

year = "2014",

month = jan,

day = "1",

doi = "10.1107/S2053229613032804",

language = "English",

volume = "70",

pages = "19--22",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "1",

}

Setifi, Z, Setifi, F, El Ammari, L, El-Ghozzi, M, Sopková-De Oliveira Santos, J, Merazig, H & Glidewell, C 2014, 'Poly[[chlorido-(1,10-phenanthroline-κ²N,N′)copper(II)]-μ₃-1,1,3,3-tetra-cyano-2-eth-oxy-propenido- κ³N:N′:N′′]: coordination polymer sheets linked into bilayers by hydrogen bonds', Acta Crystallographica Section C: Crystal Structure Communications, vol. 70, no. 1, pp. 19-22. https://doi.org/10.1107/S2053229613032804

Poly[[chlorido-(1,10-phenanthroline-κ²N,N′)copper(II)]-μ₃-1,1,3,3-tetra-cyano-2-eth-oxy-propenido- κ³N:N′:N′′]: coordination polymer sheets linked into bilayers by hydrogen bonds. / Setifi, Z.; Setifi, F.; El Ammari, L. et al.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 70, No. 1, 01.01.2014, p. 19-22.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Poly[[chlorido-(1,10-phenanthroline-κ2N,N′)copper(II)]-μ3-1,1,3,3-tetra-cyano-2-eth-oxy-propenido- κ3N:N′:N′′]

T2 - coordination polymer sheets linked into bilayers by hydrogen bonds

AU - Setifi, Z.

AU - Setifi, F.

AU - El Ammari, L.

AU - El-Ghozzi, M.

AU - Sopková-De Oliveira Santos, J.

AU - Merazig, H.

AU - Glidewell, C.

N1 - The authors acknowledge the Algerian DG–RSDT (Direction Generale de la Recherche Scientifique et du Developpement Technologique) and the Algerian ATRST (Agence Thematique de Recherche en Sciences et Technologie; PNR project) for financial support. ZS thanks Sandra Lebaroud for her help in preparing the manuscript and the Unit of Support for Technical and Scientific Research (UATRS, CNRST) for the X-ray measurements.

PY - 2014/1/1

Y1 - 2014/1/1

N2 - In the title compound, [Cu(C9H5N4O)Cl(C12H8N2)] n or [Cu(tcnoet)Cl(phen)] n , where phen is 1,10-phenanthroline and tcnoet is 1,1,3,3-tetra-cyano-2-eth- oxy-propenide, the axially elongated (4 + 2) coordination polyhedron around the CuII centre contains N atoms from three different tcnoet ligands. The resulting coordination polymer takes the form of sheets which are linked in pairs by a single C - H⋯N hydrogen bond to form bilayers. The bond lengths provide evidence for significant bond fixation in the phen ligand and extensive electronic delocalization in the tcnoet ligand, where the two -C(CN)2 units are rotated, in conrotatory fashion, out of the plane of the central C3O fragment.

AB - In the title compound, [Cu(C9H5N4O)Cl(C12H8N2)] n or [Cu(tcnoet)Cl(phen)] n , where phen is 1,10-phenanthroline and tcnoet is 1,1,3,3-tetra-cyano-2-eth- oxy-propenide, the axially elongated (4 + 2) coordination polyhedron around the CuII centre contains N atoms from three different tcnoet ligands. The resulting coordination polymer takes the form of sheets which are linked in pairs by a single C - H⋯N hydrogen bond to form bilayers. The bond lengths provide evidence for significant bond fixation in the phen ligand and extensive electronic delocalization in the tcnoet ligand, where the two -C(CN)2 units are rotated, in conrotatory fashion, out of the plane of the central C3O fragment.

KW - Crystal structure

KW - Coordination polymer

KW - Hydrogen bonding

KW - Anionic polynitrile ligands

KW - Tcnoet ligands

KW - 1,1,3,3-tetracyano-2-ethoxypropenide

KW - (4+2) coordination polyhedron

KW - Copper complex

UR - https://www.scopus.com/pages/publications/84901925164

UR - http://scripts.iucr.org/cgi-bin/sendsup?sk3522

U2 - 10.1107/S2053229613032804

DO - 10.1107/S2053229613032804

M3 - Article

AN - SCOPUS:84901925164

SN - 0108-2701

VL - 70

SP - 19

EP - 22

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 1

ER -

Setifi Z, Setifi F, El Ammari L, El-Ghozzi M, Sopková-De Oliveira Santos J, Merazig H et al. Poly[[chlorido-(1,10-phenanthroline-κ²N,N′)copper(II)]-μ₃-1,1,3,3-tetra-cyano-2-eth-oxy-propenido- κ³N:N′:N′′]: coordination polymer sheets linked into bilayers by hydrogen bonds. Acta Crystallographica Section C: Crystal Structure Communications. 2014 Jan 1;70(1):19-22. doi: 10.1107/S2053229613032804