Poly[3-methylpyridinium [(µ2-dihydrogen phosphito)bis(µ3-hydrogenphosphito)dizinc]

Jago G. Love-Jennings; Aidan McKay; David Bradford Cordes; William T.A. Harrison

doi:10.1107/S2414314624003456

Poly[3-methylpyridinium [(µ₂-dihydrogen phosphito)bis(µ₃-hydrogenphosphito)dizinc]

Jago G. Love-Jennings, Aidan McKay, David Bradford Cordes, William T.A. Harrison^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, {C₆H₈N.[Zn₂(HPO₃)₂(H₂PO₃)]}_n, the constituent ZnO₄, HPO₃ and H₂PO₃ polyhedra of the inorganic component are linked into (010) sheets by Zn—O—P bonds (mean angle = 134.4°) and the layers are reinforced by O—H···O hydrogen bonds. The protonated templates are anchored to the inorganic sheets via bifurcated N —H···(O,O) hydrogen bonds.

Original language	English
Article number	x240345
Number of pages	7
Journal	IUCrData
Volume	9
Issue number	4
DOIs	https://doi.org/10.1107/S2414314624003456
Publication status	Published - 30 Apr 2024

Keywords

Crystal structure
Zincophosphite
Layered structure
Bifurcated hydrogen bond

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10.1107/S2414314624003456Licence: CC BY

Jennings_2024_IUCrData_Poly[3-methylpyridinium [(µ2-dihydrogen phosphito)bis(µ3-hydrogenphosphito)dizinc]_CC
Copyright 2024 The authors. This article has been published under a CC BY 4.0 licence (https://creativecommons.org/licenses/by/4.0/).
Final published version, 1.69 MBLicence: CC BY

Cite this

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title = "Poly[3-methylpyridinium [(µ2-dihydrogen phosphito)bis(µ3-hydrogenphosphito)dizinc]",

abstract = "In the title compound, {C6H8N.[Zn2(HPO3)2(H2PO3)]}n, the constituent ZnO4, HPO3 and H2PO3 polyhedra of the inorganic component are linked into (010) sheets by Zn—O—P bonds (mean angle = 134.4°) and the layers are reinforced by O—H···O hydrogen bonds. The protonated templates are anchored to the inorganic sheets via bifurcated N —H···(O,O) hydrogen bonds.",

keywords = "Crystal structure, Zincophosphite, Layered structure, Bifurcated hydrogen bond",

author = "Love-Jennings, {Jago G.} and Aidan McKay and Cordes, {David Bradford} and Harrison, {William T.A.}",

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T1 - Poly[3-methylpyridinium [(µ2-dihydrogen phosphito)bis(µ3-hydrogenphosphito)dizinc]

AU - Love-Jennings, Jago G.

AU - McKay, Aidan

AU - Cordes, David Bradford

AU - Harrison, William T.A.

PY - 2024/4/30

Y1 - 2024/4/30

N2 - In the title compound, {C6H8N.[Zn2(HPO3)2(H2PO3)]}n, the constituent ZnO4, HPO3 and H2PO3 polyhedra of the inorganic component are linked into (010) sheets by Zn—O—P bonds (mean angle = 134.4°) and the layers are reinforced by O—H···O hydrogen bonds. The protonated templates are anchored to the inorganic sheets via bifurcated N —H···(O,O) hydrogen bonds.

AB - In the title compound, {C6H8N.[Zn2(HPO3)2(H2PO3)]}n, the constituent ZnO4, HPO3 and H2PO3 polyhedra of the inorganic component are linked into (010) sheets by Zn—O—P bonds (mean angle = 134.4°) and the layers are reinforced by O—H···O hydrogen bonds. The protonated templates are anchored to the inorganic sheets via bifurcated N —H···(O,O) hydrogen bonds.

KW - Crystal structure

KW - Zincophosphite

KW - Layered structure

KW - Bifurcated hydrogen bond

U2 - 10.1107/S2414314624003456

DO - 10.1107/S2414314624003456

M3 - Article

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JO - IUCrData

JF - IUCrData

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