Polar ordering of polar octahedra in [C2N2H10][VOF4(H2O)].

N.F. Stephens; Manfred Buck; Philip Lightfoot

doi:10.1039/b508959j

Polar ordering of polar octahedra in [C₂N₂H₁₀][VOF₄(H₂O)].

N.F. Stephens, Manfred Buck, Philip Lightfoot

Research output: Contribution to journal › Article › peer-review

Abstract

[C2N2H10][VOF4(H2O)] spontaneously crystallises in the polar space group P2(1); strongly distorted V- centred octahedral units form polar chains via head-to-tail H-bonding which, in turn, cooperate via the organic template to form a crystal exhibiting a strong SHG signal. It is suggested that the polar ordering arises from a preference for misalignment of the polar octahedra with the polar chain direction, leading to favourable, asymmetric template - chain H- bonding interactions.

Original language	English
Pages (from-to)	4298
Number of pages	4298
Journal	Journal of Materials Chemistry
Volume	15
DOIs	https://doi.org/10.1039/b508959j
Publication status	Published - 2005

Keywords

CRYSTAL-STRUCTURE
INORGANIC CHAINS
CS2<VOF4(H2O)>
FRAMEWORKS
MOLECULES
HOST

Access to Document

10.1039/b508959j

Cite this

@article{f9e9ed94918e4d82924805f01a8bf7b9,

title = "Polar ordering of polar octahedra in [C2N2H10][VOF4(H2O)].",

abstract = "[C2N2H10][VOF4(H2O)] spontaneously crystallises in the polar space group P2(1); strongly distorted V- centred octahedral units form polar chains via head-to-tail H-bonding which, in turn, cooperate via the organic template to form a crystal exhibiting a strong SHG signal. It is suggested that the polar ordering arises from a preference for misalignment of the polar octahedra with the polar chain direction, leading to favourable, asymmetric template - chain H- bonding interactions.",

keywords = "CRYSTAL-STRUCTURE, INORGANIC CHAINS, CS2<VOF4(H2O)>, FRAMEWORKS, MOLECULES, HOST",

author = "N.F. Stephens and Manfred Buck and Philip Lightfoot",

year = "2005",

doi = "10.1039/b508959j",

language = "English",

volume = "15",

pages = "4298",

journal = "Journal of Materials Chemistry",

issn = "0959-9428",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - Polar ordering of polar octahedra in [C2N2H10][VOF4(H2O)].

AU - Stephens, N.F.

AU - Buck, Manfred

AU - Lightfoot, Philip

PY - 2005

Y1 - 2005

N2 - [C2N2H10][VOF4(H2O)] spontaneously crystallises in the polar space group P2(1); strongly distorted V- centred octahedral units form polar chains via head-to-tail H-bonding which, in turn, cooperate via the organic template to form a crystal exhibiting a strong SHG signal. It is suggested that the polar ordering arises from a preference for misalignment of the polar octahedra with the polar chain direction, leading to favourable, asymmetric template - chain H- bonding interactions.

AB - [C2N2H10][VOF4(H2O)] spontaneously crystallises in the polar space group P2(1); strongly distorted V- centred octahedral units form polar chains via head-to-tail H-bonding which, in turn, cooperate via the organic template to form a crystal exhibiting a strong SHG signal. It is suggested that the polar ordering arises from a preference for misalignment of the polar octahedra with the polar chain direction, leading to favourable, asymmetric template - chain H- bonding interactions.

KW - CRYSTAL-STRUCTURE

KW - INORGANIC CHAINS

KW - CS2<VOF4(H2O)>

KW - FRAMEWORKS

KW - MOLECULES

KW - HOST

UR - http://www.scopus.com/inward/record.url?scp=27544503500&partnerID=8YFLogxK

U2 - 10.1039/b508959j

DO - 10.1039/b508959j

M3 - Article

SN - 0959-9428

VL - 15

SP - 4298

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

ER -

Polar ordering of polar octahedra in [C₂N₂H₁₀][VOF₄(H₂O)].

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this