Polar alicyclic rings: synthesis and structure of all cis-1,2,3,4-tetrafluorocyclopentane

Zeguo Fang; Nawaf Al-Maharik; Alexandra M. Z. Slawin; Michael Buehl; David O'Hagan

doi:10.1039/C6CC01348A

Polar alicyclic rings: synthesis and structure of all cis-1,2,3,4-tetrafluorocyclopentane

Zeguo Fang, Nawaf Al-Maharik, Alexandra M. Z. Slawin, Michael Buehl, David O'Hagan

Research output: Contribution to journal › Article › peer-review

Abstract

The all-cis isomer of 1,2,3,4-tetrafluorocyclopentane is prepared and characterised by NMR and X-ray crystallography and the experimental structure compared with theory. The structure has a similarly high polarity to all-cis tetrafluorocyclohexanes despite the increased conformational flexibility of a cyclopentane.

Original language	English
Pages (from-to)	5116-5119
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	29
Early online date	11 Mar 2016
DOIs	https://doi.org/10.1039/C6CC01348A
Publication status	Published - 14 Apr 2016

Access to Document

10.1039/C6CC01348A

FangTetrafluoroCycopentane4thMarch
Copyright 2016 the Authors. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1039/C6CC01348A
Accepted author manuscript, 582 KB

Novel organofluorine motifs: Novel organofluorine motifs in the service of industry
O'Hagan, D. (PI)
EPSRC
1/03/14 → 28/02/17
Project: Standard

Data underpinning - Polar alicyclic rings: Synthesis and structure of all cis-1,2,3,4-tetrafluorocyclopentane
Fang, Z. (Creator), Al-Maharik, N. (Creator), Slawin, A. M. Z. (Creator), Buehl, M. (Creator) & O'Hagan, D. (Creator), University of St Andrews, 17 Mar 2016
DOI: 10.17630/91a69603-839e-4562-81fd-cbe46f6f2b88
Dataset

File

Studies on selectively fluorinated cycloalkanes
Fang, Z. (Author), O'Hagan, D. (Supervisor), 29 Jul 2020
Student thesis: Doctoral Thesis (PhD)

Cite this

@article{9793468c20db4383a03bde80d83083ab,

title = "Polar alicyclic rings: synthesis and structure of all cis-1,2,3,4-tetrafluorocyclopentane",

abstract = "The all-cis isomer of 1,2,3,4-tetrafluorocyclopentane is prepared and characterised by NMR and X-ray crystallography and the experimental structure compared with theory. The structure has a similarly high polarity to all-cis tetrafluorocyclohexanes despite the increased conformational flexibility of a cyclopentane. ",

author = "Zeguo Fang and Nawaf Al-Maharik and Slawin, {Alexandra M. Z.} and Michael Buehl and David O'Hagan",

note = "The authors are grateful to the Chinese Scholarship Council for Studentship support (ZF), to EPSRC for financial support and to the EPSRC National Mass Spectrometry Service at Swansea for analytical support. DO{\textquoteright}H thanks the Royal Society for a Wolfson Research Merit Award.",

year = "2016",

month = apr,

day = "14",

doi = "10.1039/C6CC01348A",

language = "English",

volume = "52",

pages = "5116--5119",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "29",

}

TY - JOUR

T1 - Polar alicyclic rings: synthesis and structure of all cis-1,2,3,4-tetrafluorocyclopentane

AU - Fang, Zeguo

AU - Al-Maharik, Nawaf

AU - Slawin, Alexandra M. Z.

AU - Buehl, Michael

AU - O'Hagan, David

N1 - The authors are grateful to the Chinese Scholarship Council for Studentship support (ZF), to EPSRC for financial support and to the EPSRC National Mass Spectrometry Service at Swansea for analytical support. DO’H thanks the Royal Society for a Wolfson Research Merit Award.

PY - 2016/4/14

Y1 - 2016/4/14

N2 - The all-cis isomer of 1,2,3,4-tetrafluorocyclopentane is prepared and characterised by NMR and X-ray crystallography and the experimental structure compared with theory. The structure has a similarly high polarity to all-cis tetrafluorocyclohexanes despite the increased conformational flexibility of a cyclopentane.

AB - The all-cis isomer of 1,2,3,4-tetrafluorocyclopentane is prepared and characterised by NMR and X-ray crystallography and the experimental structure compared with theory. The structure has a similarly high polarity to all-cis tetrafluorocyclohexanes despite the increased conformational flexibility of a cyclopentane.

U2 - 10.1039/C6CC01348A

DO - 10.1039/C6CC01348A

M3 - Article

SN - 1359-7345

VL - 52

SP - 5116

EP - 5119

JO - Chemical Communications

JF - Chemical Communications

IS - 29

ER -

Polar alicyclic rings: synthesis and structure of all cis-1,2,3,4-tetrafluorocyclopentane

Abstract

Access to Document

Fingerprint

Projects

Novel organofluorine motifs: Novel organofluorine motifs in the service of industry

Datasets

Data underpinning - Polar alicyclic rings: Synthesis and structure of all cis-1,2,3,4-tetrafluorocyclopentane

Student theses

Studies on selectively fluorinated cycloalkanes

Cite this