Planar P6E6 (E = Se, S) macrocycles incorporating P2N2 scaffolds

Andreas Nordheider; Tristram Chivers; Ramalingam Thirumoorthi; Ignacio Vargas-Baca; J. Derek Woollins

doi:10.1039/c2cc32809g

Planar P6E6 (E = Se, S) macrocycles incorporating P2N2 scaffolds

Andreas Nordheider, Tristram Chivers, Ramalingam Thirumoorthi, Ignacio Vargas-Baca, J. Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

Oxidation of alkali metal derivatives of the dianions [E((BuN)-Bu-t)P(mu-(NBu)-Bu-t)(2)P((NBu)-Bu-t)E](2-) (E = S, Se) with I-2 produces 15-membered macrocycles in which a planar P6E6 motif is stabilised by perpendicular P2N2 scaffolds.

Original language	English
Pages (from-to)	6346-6348
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	51
Early online date	3 May 2012
DOIs	https://doi.org/10.1039/c2cc32809g
Publication status	Published - May 2012

Keywords

Inorganic macrocycles
Oxidation

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P_Te_Chem._Comm
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Cite this

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title = "Planar P6E6 (E = Se, S) macrocycles incorporating P2N2 scaffolds",

abstract = "Oxidation of alkali metal derivatives of the dianions [E((BuN)-Bu-t)P(mu-(NBu)-Bu-t)(2)P((NBu)-Bu-t)E](2-) (E = S, Se) with I-2 produces 15-membered macrocycles in which a planar P6E6 motif is stabilised by perpendicular P2N2 scaffolds.",

keywords = "Inorganic macrocycles, Oxidation",

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T1 - Planar P6E6 (E = Se, S) macrocycles incorporating P2N2 scaffolds

AU - Nordheider, Andreas

AU - Chivers, Tristram

AU - Thirumoorthi, Ramalingam

AU - Vargas-Baca, Ignacio

AU - Woollins, J. Derek

PY - 2012/5

Y1 - 2012/5

N2 - Oxidation of alkali metal derivatives of the dianions [E((BuN)-Bu-t)P(mu-(NBu)-Bu-t)(2)P((NBu)-Bu-t)E](2-) (E = S, Se) with I-2 produces 15-membered macrocycles in which a planar P6E6 motif is stabilised by perpendicular P2N2 scaffolds.

AB - Oxidation of alkali metal derivatives of the dianions [E((BuN)-Bu-t)P(mu-(NBu)-Bu-t)(2)P((NBu)-Bu-t)E](2-) (E = S, Se) with I-2 produces 15-membered macrocycles in which a planar P6E6 motif is stabilised by perpendicular P2N2 scaffolds.

KW - Inorganic macrocycles

KW - Oxidation

UR - https://www.scopus.com/pages/publications/84862231515

U2 - 10.1039/c2cc32809g

DO - 10.1039/c2cc32809g

M3 - Article

SN - 1359-7345

VL - 48

SP - 6346

EP - 6348

JO - Chemical Communications

JF - Chemical Communications

IS - 51

ER -

Planar P6E6 (E = Se, S) macrocycles incorporating P2N2 scaffolds

Abstract

Keywords

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