Phosphorus-selenium heterocycles from the tetraphospholane (PhP)4CH2

Petr Kilian, P Bhattacharyya, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)

Abstract

Two new heterocyclic and one acyclic species were prepared by reduction/deselenation of the five-membered heterocycle PhP(Se)CH2PhP(Se)Se-2 (containing a PCPSe2 ring sequence). Deselenation with Me3SiCN led to the four-membered heterocycle PhP(Se)CH2PPh(Se)Se (containing a PCPSe ring sequence), whereas reaction with Bu3P afforded the five-membered heterocycle PhP(Se)CH2PhP(Se)SePPh (ring sequence PCPSeP) and reduction with K metal afforded the dipotassiurn salt of methylene-bis(diselenophenylphosphinic) acid [K-2(PhPSe2)(2)CH2]. The new compounds were characterised by a combination of NMR, MS and FT IR spectroscopic techniques; their structures were confirmed by single crystal X-ray analyses. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).

Original languageEnglish
Pages (from-to)1461-1467
Number of pages7
JournalEuropean Journal of Inorganic Chemistry
Publication statusPublished - Apr 2003

Keywords

  • phosphanes
  • heterocycles
  • isomers
  • phosphorus
  • selenium
  • RAY

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