Phosphite ligands in Ru-based olefin metathesis catalysts

Xavier  Bantreil; Catherine S.J. Cazin

doi:10.1007/s00706-015-1487-7

Phosphite ligands in Ru-based olefin metathesis catalysts

Xavier Bantreil, Catherine S.J. Cazin

Research output: Contribution to journal › Article › peer-review

Abstract

In this short review, we focus on the synthesis and applications of new phosphite-bearing ruthenium complexes in olefin metathesis. These complexes were designed to take advantage of a known synergistic effect between strong σ-donating NHC ligands and π-acidic phosphites. The resulting catalysts display higher stability compared to their phosphine-containing congeners. A comparative summary of their use in ring-closing metathesis, cross metathesis and ring-opening metathesis polymerization is presented as well as DFT calculations describing our mechanistic understanding.

Original language	English
Pages (from-to)	1043-1052
Journal	Monatshefte für Chemie
Volume	146
Issue number	7
Early online date	20 May 2015
DOIs	https://doi.org/10.1007/s00706-015-1487-7
Publication status	Published - Jul 2015

Keywords

Phosphite
Metal complexes
Metathesis
Coordination
Chemistry

Access to Document

10.1007/s00706-015-1487-7

Cazin_2015_CM_Phosphite_AM
© Springer-Verlag Wien 2015. Reproduced in accordance with the publisher's self-archiving policy. The final publication is available at Springer via http://dx.doi.org/10.1007/s00706-015-1487-7
Accepted author manuscript, 969 KB

Catalytic C-H bond functionalisation: Catalytic C-H bond functionalisation
Cazin, C. S. J. (PI)
The Royal Society
1/10/11 → 6/05/17
Project: Fellowship

Cite this

@article{7c82d32b23db4751876ca4d411c5d49b,

title = "Phosphite ligands in Ru-based olefin metathesis catalysts",

abstract = "In this short review, we focus on the synthesis and applications of new phosphite-bearing ruthenium complexes in olefin metathesis. These complexes were designed to take advantage of a known synergistic effect between strong σ-donating NHC ligands and π-acidic phosphites. The resulting catalysts display higher stability compared to their phosphine-containing congeners. A comparative summary of their use in ring-closing metathesis, cross metathesis and ring-opening metathesis polymerization is presented as well as DFT calculations describing our mechanistic understanding.",

keywords = "Phosphite, Metal complexes, Metathesis, Coordination, Chemistry",

author = "Xavier Bantreil and Cazin, {Catherine S.J.}",

note = "The authors gratefully acknowledge the Royal Society (University Research Fellowship to CSJC), the CNRS (Centre National de la Recherche Scientifique) and l'Universit{\'e} de Montpellier for funding. ",

year = "2015",

month = jul,

doi = "10.1007/s00706-015-1487-7",

language = "English",

volume = "146",

pages = "1043--1052",

journal = "Monatshefte f{\"u}r Chemie",

issn = "0026-9247",

publisher = "Springer",

number = "7",

}

TY - JOUR

T1 - Phosphite ligands in Ru-based olefin metathesis catalysts

AU - Bantreil, Xavier

AU - Cazin, Catherine S.J.

N1 - The authors gratefully acknowledge the Royal Society (University Research Fellowship to CSJC), the CNRS (Centre National de la Recherche Scientifique) and l'Université de Montpellier for funding.

PY - 2015/7

Y1 - 2015/7

N2 - In this short review, we focus on the synthesis and applications of new phosphite-bearing ruthenium complexes in olefin metathesis. These complexes were designed to take advantage of a known synergistic effect between strong σ-donating NHC ligands and π-acidic phosphites. The resulting catalysts display higher stability compared to their phosphine-containing congeners. A comparative summary of their use in ring-closing metathesis, cross metathesis and ring-opening metathesis polymerization is presented as well as DFT calculations describing our mechanistic understanding.

AB - In this short review, we focus on the synthesis and applications of new phosphite-bearing ruthenium complexes in olefin metathesis. These complexes were designed to take advantage of a known synergistic effect between strong σ-donating NHC ligands and π-acidic phosphites. The resulting catalysts display higher stability compared to their phosphine-containing congeners. A comparative summary of their use in ring-closing metathesis, cross metathesis and ring-opening metathesis polymerization is presented as well as DFT calculations describing our mechanistic understanding.

KW - Phosphite

KW - Metal complexes

KW - Metathesis

KW - Coordination

KW - Chemistry

U2 - 10.1007/s00706-015-1487-7

DO - 10.1007/s00706-015-1487-7

M3 - Article

SN - 0026-9247

VL - 146

SP - 1043

EP - 1052

JO - Monatshefte für Chemie

JF - Monatshefte für Chemie

IS - 7

ER -

Phosphite ligands in Ru-based olefin metathesis catalysts

Abstract

Keywords

Access to Document

Fingerprint

Projects

Catalytic C-H bond functionalisation: Catalytic C-H bond functionalisation

Cite this