Phosphino-urea chemistry: Preparation and structure of chelate and P-N Bond Cleavage Complexes.

Alexandra Martha Zoya Slawin; M Wainwright; John Derek Woollins

Phosphino-urea chemistry: Preparation and structure of chelate and P-N Bond Cleavage Complexes.

Alexandra Martha Zoya Slawin, M Wainwright, John Derek Woollins

Research output: Other contribution

26 Citations (Scopus)

Abstract

Reactions of Ph2PNRC(E)NRPPh2 proceed to give simple P,P chelate complexes when E = O but give the unexpected five-membered true heterocycle Pt[Ph2PN(Me)C(NMeH)S] Cl-2 and an unusual six-membered Pd2P2O2 ring when E = S. The X-ray structures of three examples are reported.

Original language	English
Volume	24
Publication status	Published - Feb 2000

Keywords

SUBSTITUTED N,N'-DIMETHYLTHIOUREA COMPOUNDS
BISPHOSPHORYLATED DERIVATIVES

Cite this

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title = "Phosphino-urea chemistry: Preparation and structure of chelate and P-N Bond Cleavage Complexes.",

abstract = "Reactions of Ph2PNRC(E)NRPPh2 proceed to give simple P,P chelate complexes when E = O but give the unexpected five-membered true heterocycle Pt[Ph2PN(Me)C(NMeH)S] Cl-2 and an unusual six-membered Pd2P2O2 ring when E = S. The X-ray structures of three examples are reported.",

keywords = "SUBSTITUTED N,N'-DIMETHYLTHIOUREA COMPOUNDS, BISPHOSPHORYLATED DERIVATIVES",

author = "Slawin, {Alexandra Martha Zoya} and M Wainwright and Woollins, {John Derek}",

note = "New J Chem",

year = "2000",

month = feb,

language = "English",

volume = "24",

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TY - GEN

T1 - Phosphino-urea chemistry: Preparation and structure of chelate and P-N Bond Cleavage Complexes.

AU - Slawin, Alexandra Martha Zoya

AU - Wainwright, M

AU - Woollins, John Derek

N1 - New J Chem

PY - 2000/2

Y1 - 2000/2

N2 - Reactions of Ph2PNRC(E)NRPPh2 proceed to give simple P,P chelate complexes when E = O but give the unexpected five-membered true heterocycle Pt[Ph2PN(Me)C(NMeH)S] Cl-2 and an unusual six-membered Pd2P2O2 ring when E = S. The X-ray structures of three examples are reported.

AB - Reactions of Ph2PNRC(E)NRPPh2 proceed to give simple P,P chelate complexes when E = O but give the unexpected five-membered true heterocycle Pt[Ph2PN(Me)C(NMeH)S] Cl-2 and an unusual six-membered Pd2P2O2 ring when E = S. The X-ray structures of three examples are reported.

KW - SUBSTITUTED N,N'-DIMETHYLTHIOUREA COMPOUNDS

KW - BISPHOSPHORYLATED DERIVATIVES

UR - http://www.scopus.com/inward/record.url?scp=0034009458&partnerID=8YFLogxK

M3 - Other contribution

VL - 24

ER -

Phosphino-urea chemistry: Preparation and structure of chelate and P-N Bond Cleavage Complexes.

Abstract

Keywords

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