Phosphate binding to the [Au(IPr)] moiety: inner vs. outer sphere coordination behaviour

Sylvain Gaillard; Diane Rix; Alexandra M. Z. Slawin; Jerome Lacour; Steven P. Nolan

doi:10.1039/c2dt30440f

Phosphate binding to the [Au(IPr)] moiety: inner vs. outer sphere coordination behaviour

Sylvain Gaillard, Diane Rix, Alexandra M. Z. Slawin, Jerome Lacour, Steven P. Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis and characterization of a new class of cationic (NHC) gold(I) (NHC = N-Heterocyclic carbene) complex containing the phosphate counterions TRISPHAT and TRISPHAT-N have been achieved. The selection of the appropriate hexacoordinated phosphate architecture permits the isolation of complexes bearing an inner or outer sphere anionic counterion.

Original language	English
Pages (from-to)	8235-8237
Number of pages	3
Journal	Dalton Transactions
Volume	41
Issue number	27
DOIs	https://doi.org/10.1039/c2dt30440f
Publication status	Published - 2012

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10.1039/c2dt30440f

Molecular assembly using gold catalysis: Molecular assembly using gold catalysis
Nolan, S. P. (PI)
EPSRC
1/01/10 → 31/12/12
Project: Standard

Cite this

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title = "Phosphate binding to the [Au(IPr)] moiety: inner vs. outer sphere coordination behaviour",

abstract = "The synthesis and characterization of a new class of cationic (NHC) gold(I) (NHC = N-Heterocyclic carbene) complex containing the phosphate counterions TRISPHAT and TRISPHAT-N have been achieved. The selection of the appropriate hexacoordinated phosphate architecture permits the isolation of complexes bearing an inner or outer sphere anionic counterion.",

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AU - Gaillard, Sylvain

AU - Rix, Diane

AU - Slawin, Alexandra M. Z.

AU - Lacour, Jerome

AU - Nolan, Steven P.

PY - 2012

Y1 - 2012

N2 - The synthesis and characterization of a new class of cationic (NHC) gold(I) (NHC = N-Heterocyclic carbene) complex containing the phosphate counterions TRISPHAT and TRISPHAT-N have been achieved. The selection of the appropriate hexacoordinated phosphate architecture permits the isolation of complexes bearing an inner or outer sphere anionic counterion.

AB - The synthesis and characterization of a new class of cationic (NHC) gold(I) (NHC = N-Heterocyclic carbene) complex containing the phosphate counterions TRISPHAT and TRISPHAT-N have been achieved. The selection of the appropriate hexacoordinated phosphate architecture permits the isolation of complexes bearing an inner or outer sphere anionic counterion.

U2 - 10.1039/c2dt30440f

DO - 10.1039/c2dt30440f

M3 - Article

SN - 1477-9226

VL - 41

SP - 8235

EP - 8237

JO - Dalton Transactions

JF - Dalton Transactions

IS - 27

ER -

Phosphate binding to the [Au(IPr)] moiety: inner vs. outer sphere coordination behaviour

Abstract

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Projects

Molecular assembly using gold catalysis: Molecular assembly using gold catalysis

Cite this