Phosphate binding to the [Au(IPr)] moiety: inner vs. outer sphere coordination behaviour

Sylvain Gaillard, Diane Rix, Alexandra M. Z. Slawin, Jerome Lacour, Steven P. Nolan

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

The synthesis and characterization of a new class of cationic (NHC) gold(I) (NHC = N-Heterocyclic carbene) complex containing the phosphate counterions TRISPHAT and TRISPHAT-N have been achieved. The selection of the appropriate hexacoordinated phosphate architecture permits the isolation of complexes bearing an inner or outer sphere anionic counterion.

Original languageEnglish
Pages (from-to)8235-8237
Number of pages3
JournalDalton Transactions
Volume41
Issue number27
DOIs
Publication statusPublished - 2012

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