Phosphabicyclononane-containing Ru complexes: Efficient pre-catalysts for olefin metathesis reactions

Fabien Boeda; Herve Clavier; Margaritha Jordaan; Wolfgang H. Meyer; Steven Patrick Nolan

doi:10.1021/jo702169p

Phosphabicyclononane-containing Ru complexes: Efficient pre-catalysts for olefin metathesis reactions

Fabien Boeda, Herve Clavier, Margaritha Jordaan, Wolfgang H. Meyer, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

[GRAPHICS]

The catalytic performances of three Phosphabicyclononane (Phoban)-containing ruthenium-based pre-catalysts have been evaluated for metathesis transformations. A wide screening of substrates in ring-closing metathesis reactions reveals the greater efficiency of pre-catalyst 4. Comparison of the catalytic activities of 4 with Grubbs' first-generation pre-catalyst illustrates the key role of the Phoban ligand. Additionally, a comparative study of three Phoban-containing pre-catalysts has been conducted for the self-metathesis of I-octene at low catalyst loading (25-100 ppm).

Original language	English
Pages (from-to)	259-263
Number of pages	5
Journal	The Journal of Organic Chemistry
Volume	73
Issue number	1
DOIs	https://doi.org/10.1021/jo702169p
Publication status	Published - 4 Jan 2008

Keywords

RING-CLOSING METATHESIS
FATTY-ACID ESTERS
TETRASUBSTITUTED OLEFINS
RUTHENIUM COMPLEXES
RUCL2(=CHR)(PR(3))(2)
HETEROCYCLES
LIGANDS

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title = "Phosphabicyclononane-containing Ru complexes: Efficient pre-catalysts for olefin metathesis reactions",

abstract = "[GRAPHICS]The catalytic performances of three Phosphabicyclononane (Phoban)-containing ruthenium-based pre-catalysts have been evaluated for metathesis transformations. A wide screening of substrates in ring-closing metathesis reactions reveals the greater efficiency of pre-catalyst 4. Comparison of the catalytic activities of 4 with Grubbs' first-generation pre-catalyst illustrates the key role of the Phoban ligand. Additionally, a comparative study of three Phoban-containing pre-catalysts has been conducted for the self-metathesis of I-octene at low catalyst loading (25-100 ppm).",

keywords = "RING-CLOSING METATHESIS, FATTY-ACID ESTERS, TETRASUBSTITUTED OLEFINS, RUTHENIUM COMPLEXES, RUCL2(=CHR)(PR(3))(2), HETEROCYCLES, LIGANDS",

author = "Fabien Boeda and Herve Clavier and Margaritha Jordaan and Meyer, {Wolfgang H.} and Nolan, {Steven Patrick}",

year = "2008",

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doi = "10.1021/jo702169p",

language = "English",

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journal = "The Journal of Organic Chemistry",

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T1 - Phosphabicyclononane-containing Ru complexes: Efficient pre-catalysts for olefin metathesis reactions

AU - Boeda, Fabien

AU - Clavier, Herve

AU - Jordaan, Margaritha

AU - Meyer, Wolfgang H.

AU - Nolan, Steven Patrick

PY - 2008/1/4

Y1 - 2008/1/4

N2 - [GRAPHICS]The catalytic performances of three Phosphabicyclononane (Phoban)-containing ruthenium-based pre-catalysts have been evaluated for metathesis transformations. A wide screening of substrates in ring-closing metathesis reactions reveals the greater efficiency of pre-catalyst 4. Comparison of the catalytic activities of 4 with Grubbs' first-generation pre-catalyst illustrates the key role of the Phoban ligand. Additionally, a comparative study of three Phoban-containing pre-catalysts has been conducted for the self-metathesis of I-octene at low catalyst loading (25-100 ppm).

AB - [GRAPHICS]The catalytic performances of three Phosphabicyclononane (Phoban)-containing ruthenium-based pre-catalysts have been evaluated for metathesis transformations. A wide screening of substrates in ring-closing metathesis reactions reveals the greater efficiency of pre-catalyst 4. Comparison of the catalytic activities of 4 with Grubbs' first-generation pre-catalyst illustrates the key role of the Phoban ligand. Additionally, a comparative study of three Phoban-containing pre-catalysts has been conducted for the self-metathesis of I-octene at low catalyst loading (25-100 ppm).

KW - RING-CLOSING METATHESIS

KW - FATTY-ACID ESTERS

KW - TETRASUBSTITUTED OLEFINS

KW - RUTHENIUM COMPLEXES

KW - RUCL2(=CHR)(PR(3))(2)

KW - HETEROCYCLES

KW - LIGANDS

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U2 - 10.1021/jo702169p

DO - 10.1021/jo702169p

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JO - The Journal of Organic Chemistry

JF - The Journal of Organic Chemistry

IS - 1

ER -

Phosphabicyclononane-containing Ru complexes: Efficient pre-catalysts for olefin metathesis reactions

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Keywords

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