Ph(2)PNHP(O)Ph(2), a versatile new ligand: Syntheses of monodentate and chelating complexes and a novel Pd2P4N2O2 metallocycle

M B  Smith; A M Z  Slawin; J D  Woollins

doi:10.1016/0277-5387(95)00467-X

Ph(2)PNHP(O)Ph(2), a versatile new ligand: Syntheses of monodentate and chelating complexes and a novel Pd2P4N2O2 metallocycle

M B Smith, A M Z Slawin, J D Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

Oxidation of Ph(2)PNHPPh(2) gave Ph(2)PNHP(O)Ph(2) (1), which reacted with (C3H5)PdCl2Pd(C3H5) to form (C3H5)PdCl(Ph(2)PNHP(O)Ph(2)) (2). Treatment of 2 with Ag[BF4] or Bu(t)OK yielded the almost planar five-membered PdP2NO metallocycle [(C3H5)Pd(Ph(2)PNHP(O)Ph(2))]BF4 (3) or the 'chair'-like 10-membered metallocycle [(C3H5)Pd(Ph(2)PNP(O)Ph(2))(2)Pd(C3H5)] (4) respectively.

Original language	English
Pages (from-to)	1579-1583
Number of pages	5
Journal	Polyhedron
Volume	15
Issue number	9
DOIs	https://doi.org/10.1016/0277-5387(95)00467-X
Publication status	Published - May 1996

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@article{e1305b972a944858ac47e8e27f1d0207,

title = "Ph(2)PNHP(O)Ph(2), a versatile new ligand: Syntheses of monodentate and chelating complexes and a novel Pd2P4N2O2 metallocycle",

abstract = "Oxidation of Ph(2)PNHPPh(2) gave Ph(2)PNHP(O)Ph(2) (1), which reacted with (C3H5)PdCl2Pd(C3H5) to form (C3H5)PdCl(Ph(2)PNHP(O)Ph(2)) (2). Treatment of 2 with Ag[BF4] or Bu(t)OK yielded the almost planar five-membered PdP2NO metallocycle [(C3H5)Pd(Ph(2)PNHP(O)Ph(2))]BF4 (3) or the 'chair'-like 10-membered metallocycle [(C3H5)Pd(Ph(2)PNP(O)Ph(2))(2)Pd(C3H5)] (4) respectively.",

author = "Smith, {M B} and Slawin, {A M Z} and Woollins, {J D}",

year = "1996",

month = may,

doi = "10.1016/0277-5387(95)00467-X",

language = "English",

volume = "15",

pages = "1579--1583",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

number = "9",

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TY - JOUR

T1 - Ph(2)PNHP(O)Ph(2), a versatile new ligand: Syntheses of monodentate and chelating complexes and a novel Pd2P4N2O2 metallocycle

AU - Smith, M B

AU - Slawin, A M Z

AU - Woollins, J D

PY - 1996/5

Y1 - 1996/5

N2 - Oxidation of Ph(2)PNHPPh(2) gave Ph(2)PNHP(O)Ph(2) (1), which reacted with (C3H5)PdCl2Pd(C3H5) to form (C3H5)PdCl(Ph(2)PNHP(O)Ph(2)) (2). Treatment of 2 with Ag[BF4] or Bu(t)OK yielded the almost planar five-membered PdP2NO metallocycle [(C3H5)Pd(Ph(2)PNHP(O)Ph(2))]BF4 (3) or the 'chair'-like 10-membered metallocycle [(C3H5)Pd(Ph(2)PNP(O)Ph(2))(2)Pd(C3H5)] (4) respectively.

AB - Oxidation of Ph(2)PNHPPh(2) gave Ph(2)PNHP(O)Ph(2) (1), which reacted with (C3H5)PdCl2Pd(C3H5) to form (C3H5)PdCl(Ph(2)PNHP(O)Ph(2)) (2). Treatment of 2 with Ag[BF4] or Bu(t)OK yielded the almost planar five-membered PdP2NO metallocycle [(C3H5)Pd(Ph(2)PNHP(O)Ph(2))]BF4 (3) or the 'chair'-like 10-membered metallocycle [(C3H5)Pd(Ph(2)PNP(O)Ph(2))(2)Pd(C3H5)] (4) respectively.

U2 - 10.1016/0277-5387(95)00467-X

DO - 10.1016/0277-5387(95)00467-X

M3 - Article

SN - 0277-5387

VL - 15

SP - 1579

EP - 1583

JO - Polyhedron

JF - Polyhedron

IS - 9

ER -

Ph(2)PNHP(O)Ph(2), a versatile new ligand: Syntheses of monodentate and chelating complexes and a novel Pd2P4N2O2 metallocycle

Abstract

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